СПЕКТРОСКОПИЧЕСКИ И / ИЛИ СТРУКТУРНО ИНТРИГУЮЩИЕ ФТАЛОЦИАНИНЫ И ПОДОБНЫЕ СОЕДИНЕНИЯ. ЧАСТЬ 3. ДИМЕРНЫЕ СИСТЕМЫ, ТЕТРАМЕРЫ И ВЫВОДЫ
Аннотация
Данная работа является третьей частью обзора, в котором представлены свойства большой группы фталоцианинов, которые были синтезированы и спектроскопически и теоретически изучены в работах, выполненных под руководством автора за период 2007-2017 гг. Приведены примеры анализа спектроскопических данных в сочетании с квантово-химическими расчетами различного уровня. В качестве спектроскопических методов использовалсь методы электронного поглощения, естественного и магнитного кругового дихроизма (CD и MCD) флуоресценции, фосфоресценции и электронного парамагнитного резонанса с временным разрешением. На основе квантово-химических расчетов теоретически проанализированы спектры (4n + 2) p систем, а также некоторые 4np антиароматических систем. В отличие от первой и второй частей обзора, в данной части рассматриваются димерные и тетрамерные системы.
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Литература
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