EXTRACTION OF RUBBER FROM LATEX BY HYBRID COAGULANT BASED ON POLYDIMETHYLDIALLYLAMMONIUM CHLORIDE AND VISCOSE FIBER

  • Nadezhda S. Nikulina Department of Special Training of Voronezh Institute for Advanced Training of Employees of the State Fire Service of the Ministry of the Russian Federation for Civil Defense
  • Inna N. Pugacheva Faculty of Ecology and Chemical Technology of Voronezh State University of Engineering Technology
  • Vyacheslav M. Misin N.M. Emanuel Institute of Biochemical Physics of the RAS
  • Viktor N. Verezhnikov Departments of High-Molecular Compounds and Colloids of Voronezh State University
  • Natalia Yu. Sannikova Polymer Processing and Technosphere Safety of Voronezh State University of Engineering Technology
  • Sergey S. Nikulin Polymer Processing and Technosphere Safety of Voronezh State University of Engineering Technology
Keywords: latex, viscose fiber, polydimethyldiallylammonium chloride, coagulation, vulcanizates

Abstract

In the proposed work, the possibility of using a hybrid coagulant based on a polymer cationic electrolyte-VPK – 402 (poly-N,N-dimethyl-N, N-diallylammonium chloride) in combination with viscose fiber in the technological process of separating SKS-30 ark rubber from latex is considered. The influence of the consumption of a hybrid coagulating agent, viscose fiber and its dosage, as well as the process temperature on the reduction of the aggregate stability of styrene-butadiene latex is considered. The influence of viscose fiber on the physical and mechanical properties of vulcanizates is established. At the same time, a number of features were noted consisting in a decrease in the aggregate stability of latex butadiene-styrene rubber during its coagulation with a hybrid coagulant. It was found that the use of a hybrid coagulant can reduce the consumption of cationic polyelectrolyte by up to 30%. It is shown that in the multicomponent system under consideration, several processes can occur simultaneously, which lead to the destabilization of latex dispersions. The use of a hybrid coagulant, including cationic polyelectrolyte, provides a combined effect of the bridging and neutralization mechanisms of violation of the aggregate stability of the dispersion. The presence of viscose fiber in the dispersed phase leads to an additional coagulating effect-adagulation, which is a kind of heterocoagulation. This may be due to the difference in surface potentials between the latex globules and the fiber additive. It is established that the temperature regime of the process of isolation of rubber from latex does not significantly affect the completeness of the extraction of rubber from latex. A decrease in the content of components of the emulsion system in wastewater discharged from the shops producing rubbers by emulsion polymerization was noted. According to the main physical and mechanical parameters, rubbers, rubber mixtures and vulcanizates prepared on their basis meet the requirements.

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Published
2021-05-15
How to Cite
Nikulina, N. S., Pugacheva, I. N., Misin, V. M., Verezhnikov, V. N., Sannikova, N. Y., & Nikulin, S. S. (2021). EXTRACTION OF RUBBER FROM LATEX BY HYBRID COAGULANT BASED ON POLYDIMETHYLDIALLYLAMMONIUM CHLORIDE AND VISCOSE FIBER. ChemChemTech, 64(6), 62-68. https://doi.org/10.6060/ivkkt.20216406.6356
Section
CHEMICAL TECHNOLOGY (inorganic and organic substances. Theoretical fundamentals)