ФИЗИКО-ХИМИЧЕСКИЕ СВОЙСТВА ПЛАЗМЫ РАЗРЯДА ПОСТОЯННОГО ТОКА С ЖИДКИМ КАТОДОМ
Аннотация
В статье анализируются результаты экспериментальных исследований и моделирования физико-химических характеристик плазмы разрядов постоянного тока с электролитным катодом при давлениях (1,01-0,101)·105 Па, создаваемой в молекулярных и атомарных газах. Приводятся сведения о физических параметрах плазмы (напряженности электрических полей, катодные падения потенциала, газовые температуры). Анализируются результаты измерений и расчетов концентраций активных частиц, электронов, а также распределений молекул по колебательным уровням и функциях распределения электронов по энергиям.
Литература
Bruggeman P., Leys C. Non-thermal plasmas in and in contact with liquids. J. Phys. D: Appl. Phys. 2009. V. 42. N 5. P. 053001. DOI: 10.1088/0022-3727/42/5/053001.
Tatarova E., Bundaleska N., Sarrette L.Ph., Ferreira C.M. Plasmas for environmental issues: from hydrogen production to 2D materials assembly. Plasma Sources Sci. Technol. 2014. V. 23. N 6. P. 063002. DOI: 10.1088/0963-0252/23/6/063002.
Jiang B., Zheng J., Qiu S., Wu M., Zhang Q., Yan Z., Xue Q. Review on electrical discharge plasma technology for wastewater remediation. Chem. Ing. J. 2014. V. 236. P. 348. DOI: 10.1016/j.cej.2013.09.090.
Locke B.R., Mededovic Thagard S.M. Analysis and Re-view of Chemical Reactions and Transport Processes in Pulsed Electrical Discharge Plasma Formed Directly in Liquid Water. Plasma Chem. Plasma Process. 2012. V. 32. N 5. P. 875.
Bobkova E.S., Grinevich V.I., Isakina A.A., Rybkin V.V. Decomposition of organic substances in aqeous solutions under action of electric discharges of atpospheric pressure. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2011. V. 54. N 6. P. 3-17 (in Russian).
Fridman A. Plasma Chemistry. Cambrige University Press. 2008. 978 p.
Choi H.S., Shikova T.G., Titov V.A., Rybkin V.V. Sur-face oxidation of polyethylene using an atmospheric pressure glow discharge with liquid electrolyte cathode. J. Colloid. Interface Sci. 2006. V. 300. N 2. P. 640.
Misra N.N. The contribution of non-thermal and advanced oxidation technologies towards dissipation of pesticide resi-dues. Trends Food Sci. Technol. 2015. V. 45. N 2. P. 229.
Mu R., Liu Y., Li R., Xue G., Ognier S. Remediation of pyrene-contaminated soil by active species generated from flat-plate dielectric barrier discharge. Chem. Ing. J. 2016. DOI: 10.1016/j.cej.2016.03.106.
Bobkova Е., Smirnov S., Zalipaeva Yu., Rybkin V. Mo-deling Chemical Composition for an Atmospheric Pressure DC Discharge in Air with Water Cathode by 0-D model. Plasma Chem. Plasma Process. 2014. V. 34. N 4. P. 721.
Shutov D., Smirnov S., Bobkova E., Rybkin V. Ionization Mechanism and Chemical Composition of an Argon DC Discharge with Water Cathode. Plasma Chem. Plasma Process. 2015. V. 35. N 1. P. 107. DOI: 10.1007/s11090-014-9596-3.
Smirnov S., Shutov D., Bobkova E., Rybkin V. Physical Parameters and Chemical Composition of a Nitrogen DC Discharge with Water Cathode. Plasma Chem. Plasma Process. 2015. V. 35. N 4. P. 639. DOI: 10.1007/s11090-015-9626-9.
Smirnov S., Shutov D., Bobkova E., Rybkin V. Chemical Composition, Physical Properties and Populating Mecha-nism of Some O(I) States for a DC Discharge in Oxygen withWaterCathode. Plasma Chem. Plasma Process. 2016. V. 36. N 2. P. 415.
Li L., Nikiforov A., Xiong Q., Lu X., Taghizadeh L., Leys C. Measurement of OH radicals at state X 2Π in an atmospheric-pressure micro-flow dc plasma with liquid electrodes in He, Ar and N2 by means of laser-induced fluorescence spectroscopy. J. Phys. D: Appl. Phys. 2012.
V. 45. N 12. P. 125201.
Bruggeman P., Liu J.J., Degroote J., Kong M.G., Vierendeels J., Leys C. DC excited glow discharges in at-mospheric pressure air in pin-to-water electrode systems. J. Phys. D: Appl. Phys. 2008. V. 41. N 7. P. 215201.
Titov V.A., Rybkin V.V., Maximov A.I., Choi H.S. Char-acteristics of atmospheric pressure glow discharge with aqueous electrolyte cathode. Plasma Chem. Plasma Pro-cess. 2005. V. 25. N 5. P. 503.
Cserfalvi T., Mezei P. Operating mechanism of the electro-lyte cathode atmospheric glow discharge. Fresenius J. Anal. Chem. 1996. V. 355. N 7-8. P. 813.
Gaisin A.R., Son E.E. Vapor air discharges between elec-trolytic cathode and metal anode at atmospheric pressure. High Temperature. 2005. V. 43. N 1. P. 1.
Bruggeman P., Rubezl E., Maslani A., Degroote J., Malesevic A., Rego R., Vierendeels J., Leys C. Character-istics of atmospheric pressure air discharges with a liquid cathode and a metal anode. Plasma Sources Sci. Technol. 2008. V. 17. N 2. P. 025012.
Bobkova E.S., Shikova T.G., Grinevich V.I., Rybkin V.V. Mechanism of hydrogen peroxide formation in elec-trolytic-cathode atmospheric-pressure direct-current dis-charge. High Energy Chemistry. 2012. V. 46. N 1. P. 56.
Verreysken T., Schram D.C., Leys C., Bruggeman P. Spectroscopic study of an atmospheric dc glow discharge with a water electrode in atomic and molecular gases. Plasma Sources Sci. Technol. 2010. V. 19. N 4. P. 045004.
Mezei P., Cserfalvi T. The investigation of an abnormal electrolyte cathode atmospheric glow discharge (ELCAD). J. Phys. D: Appl. Phys. 2006. V. 39. N 12. P. 2534.
Lu X.P., Laroussi M. Atmospheric pressure glow discharge in air using a water electrode. IEEE Trans. Plasma Sci. 2005. V. 33. P. 272.
Titov V.A., Rybkin V.V., Smirnov S.A., Kulentsan A.N., Choi H.S. Experimental and theoretical studies on the char-acteristics of atmospheric pressure glow discharge with liq-uid cathode. Plasma Chem. Plasma Process. 2006. V. 26. N 6. P. 543.
Konovalov A.S., Golubev S.N., Ivanov A.N., Shutov D.A., Smirnov S.A., Rybkin V.V. Electro-physical param-eters of glow discharge with liquid electrode in air medium at lower pressure. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2012. V. 55. N 12. P. 55 (in Russian).
Jamrôz P., Zyrnicki W. Spectroscopic Characterization of Miniaturized Atmospheric-Pressure dc Glow Discharge Generated in Contact with Flowing Small Size Liquid Cathode. Plasma Chem. Plasma Process. 2011. V. 31. N 5. P. 681.
Xiong Q., Yang Z., Bruggeman P.J. Absolute OH density measurements in an atmospheric pressure dc glow discharge in air with water electrode by broadband UV absorption spectroscopy. J. Phys. D: Appl. Phys. 2015. V. 48. N 9. P. 424008. DOI: 10.1088/0022-3727/48/42/424008.
Webb M.R., Andrade F.J., Gamez G., McCrindle R., Hieftje G.H. Spectroscopic characterization of ion and electron populations in a solution-cathode glow discharge. J. Anal. At. Spectrom. 2005. V. 20. N 11. P. 1218.
Nikiforov A., Xiong Q., Britun N., Snyders R., Lu X.P., Leys C. Absolute Concentration of OH Radicals in Atmos-pheric Pressure Glow Discharges with a Liquid Electrode Measured by Laser-Induced Fluorescence Spectroscopy. Appl. Phys. Express. 2011. V. 4. N 2. P. 026102.
Bruggeman P., Schram D., Gonzalez M.A., Rego R., Kong M.G., Leys C. Characterization of a direct dc-excited discharge in water by optical emission spectroscopy. Plasma Sources Sci. Technol. 2009. V. 18. N 2. P. 025017.
Rybkin V.V., Smirnov S.A., Titov V.A., Arzhakov D.A. The characteristics of electrons and vibrational distributions of molecules in an atmospheric-pressure liquid-cathode DC discharge in air. High Temperature. 2010. V. 48. N 4. P. 476.
Ginzburg V.L., Gurevich A.V. Non-linear phenomena in a plasma in alternative electro-magnetic field. UFN. 1960. V. LXX. N 2. P. 201 (in Russian).
Rybkin V.V., Titov V.A., Kholodkov I.V. Kinetic parame-ters and cross-sections of interaction of electrons with water molecules. Izv Vyssh Uchebn Zaved Khim Khim Tekhnol. 2008. V. 51. N 3. P. 3 (in Russian).
Bobkova E.S., Rybkin V.V. Estimation of electron param-eters in the dielectric barrier discharge with a liquid electrode at atmospheric pressure. High Temperature. 2013. V. 51. N 6. P. 747.
Konovalov A.S., Rybkin V.V., Smirnov S.A. Influence of water molecules on electron parameters in non-equilibrium air plasma. Izv Vyssh Uchebn Zaved Khim Khim Tekhnol. 2013. V. 56. N 11. P. 44 (in Russian).
Barinov Y.A., Skol’nik S.M. Probe measurements in a discharge with liquid nonmetallic electrodes in air at atmos-pheric pressure. Tech. Phys. 2002. V. 47. N 3. P. 313.
Chen Q., Sato K., Takemura Y., Shirai H. Physico-chemistry of the plasma-electrolyte solution interface. Thin Solid Films. 2008. V. V. 516. N 19. P. 6688.
Mezei P., Cserfaly T., Janossy M. The gas temperature in the cathode surface - dark space boundary layer of an elec-trolyte cathode atmospheric glow discharge (ELCAD). J. Phys. D: Appl. Phys. 1998. V. 31. N 4. L. 14.
Nikiforov A.Yu., Leys Ch., Gonzalez M.A., Walsh J.L. Electron density measurement in atmospheric pressure plasma jets: Stark broadening of hydrogenated and non-hydrogenated lines. Plasma Sources Sci. Technol. 2015. V. 24. N 3. P. 034001.
Barinov Yu.A., Shkol’nik S.M. Zhurn. Tekh. Fiziki. 2002. V. 72. N 3. P. 31 (in Russian).
Gigososa M.A., Gonzaez M.A., Cardenoso V. Computer simulated Balmer-alpha, -beta and -gamma Stark line profiles for non-equilibrium plasmas diagnostics. Spectrochim Acta B. 2003. V. 58. N 8. P. 1489. DOI: 10.1016/S0584-8547(03)00097-1.
Mezei P., Cserfalvi T., Csillag L. The spatial distribution of the temperatures and the emitted spectrum in the electrolyte cathode atmospheric glow discharge. J. Phys. D: Appl. Phys. 2005. V. 38. N 16. P. 2804. DOI: 10.1088/0022-3727/38/16/010.
Maksimov A.I., Titov V.A., Khlyustova A.V. Electrolyte-as-Cathode Glow Discharge Emission and the Processes of Solution-to-Plasma Transport of Neutral and Charged Spe-cies. High Energy Chemistry. 2004. V. 38. N 3. P. 196.
Cserfalvi T., Mezei P., Apai P. Emission studies on a glow discharge in atmospheric pressure air using water as a cath-ode. J. Phys. D: Appl. Phys. 1993. N 26. P. 2184.
Mezei P., Cserfalvi T., Kim H.J., Mohammad A., Mottaleb M.A. Analyst. 2001. V. 126. N 5. P. 712. DOI: 10.1039/b010057i.
Nikiforov A. Measurement of OH radicals density in plasma of DC discharge above electrolyte by means of laser-induced fluorescence spectroscopy. Proceedings of the VI International Symposium on Theoretical and Applied Plasma Chemistry. Russia. Ivanovo, 3-9 Sept. 2011. Ivanovo: ISUCT. 2011. P. 318.
Mezei P., Cserfalli T. A Critical Review of Published Data on the Gas Temperature and the Electron Density in the Electrolyte Cathode Atmospheric Glow Discharges. Sensors. 2012. V. 12. N 5. P. 6576.
Bobkova E.S., Rybkin V.V. Analysis of Applicability of Translational Factor Approximations to Calculation of Vi-brational Exchange Rate Constants in the N2–O2 System under Low Pressure Discharge Conditions. High Energy Chemistry. 2016. V. 50. N 2. P. 139.
