SYNTHESIS AND STUDY OF INHIBITORY PROPERTIES OF QATERNARY AMMONIUM SALTS BASED ON AMINOETHYLETHANOLAMINE

  • Svetlana S. Katkova Bashkir State University
  • Vera I. Levashova Bashkir State University
Keywords: petroleum production, sulfate-reducing bacteria, corrosion inhibitor, bactericide, aminoethylethanola-mine, benzyl chloride, quaternary ammonium salt, synthesis, corrosion rate, bactericidal activity

Abstract

This article is devoted to the topical today biological corrosion problem of steel under the conditions of production, transportation and refining. The characteristics of corrosion caused by the vital activity of sulfate-reducing bacteria were analyzed. The article seeks to examine the effectiveness of new ammonium salts based on aminoethylethanolamine as reagents possessing inhibitory and antibacterial properties. The main content of the research is the analysis of the synthesis of new compounds based on ammonium aminoethylethanolamine and benzyl chloride. The optimal conditions of the synthesis were determined on the basis of the effect of temperature, reaction time, molar ratio of the final product output. The considerable attention was devoted to testing obtained new metal ammonium salts as acid corrosion inhibitors, including determining the corrosion rate and the degree of protection.  The comparison of the results of the evaluation of the inhibitory properties of synthesized salts is presented using the rate indicator of corrosion "Monicor-2M" and gravimetric method. The results of the evaluation of bactericidal activity of the synthesized compounds were obtained with the determining the degree of suppression of sulfate-reducing bacteria SRB culture using isolated from natural sources and identified as Desulfovibrio desulfuricans. The results showed a high level of protective action of synthesized salts and their possible use in the oil industry.

Forcitation:

Katkova S.S., Levashova V.I. Synthesis and study of inhibitory properties of qaternary ammonium salts based on aminoethylethanolamine. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2017. V. 60. N 3. P. 72-76.

References

Sukhotin A.M., Bogachev A.F., Palmsky V.G. The corrosion resistance of the equipment of chemical plants. Corrosion under the effect of heat transfer fluids, refrigerants and working fluids. L.: Khimiya. 1988. 360 p. (in Russian).

Ibragimov N.G., Khafizov A.R., Shaiydakov V.V. Complications in oil production. Ufa: Publisher of scientific literature "Мonographia". 2003. 302 p. (in Russian).

Levashova V.I., Kazakova E.V. Nitrogen-containing organic corrosion inhibitors for the oil industry. Sterlitamak: Sterlitamak fil. Bashkir State University. 2015. 102 p. (in Russian).

Charlo G. Methods of Analytical Chemistry. M.-L.: Khimiya. 1965. 895 p. (in Russian).

GOST 9.506-09. Metal corrosion inhibitors in aqueous media oil. Method for determination of protective ability. M.: Publisher IPC Standards. 2009. 16 p. (in Russian).

Method of controlling microbial infestation of oilfield waters and evaluation of the protective action of the reagents / RD 39-3-973-83. Ufa: VNIISPT 2004. 36 p. (in Russian).

Published
2017-04-13
How to Cite
Katkova, S. S., & Levashova, V. I. (2017). SYNTHESIS AND STUDY OF INHIBITORY PROPERTIES OF QATERNARY AMMONIUM SALTS BASED ON AMINOETHYLETHANOLAMINE. ChemChemTech, 60(3), 72-76. https://doi.org/10.6060/tcct.2017603.5484
Section
CHEMICAL TECHNOLOGY (inorganic and organic substances. Theoretical fundamentals)