CO-CRYSTALLIZATION OF C60 AND С70 FULLERENES IN CRYSTAL-SOLVATE [(C70)X+(С60)Y]• TMTSeF•2(C6H6) (х+у=3)

  • Maksim A. Blagov MSU
  • Nataliya G. Spitsina Institute of Problems of Chemical Physics of RAS
  • Sergei V. Konovalikhin Institute of Structural Macrokinetics and Materials Science of RAS
Keywords: С60, C70 fullerenes, tetramethyl(tetra selenium)fulvalene (TMTSF), powder X-ray crystallography, crystal-chemical modeling, IR spectroscopy, electroconductivity

Abstract

The compexation of (С70/C60) fullerenes with organic p-donor of electrons tetramethyl-(tetra selenium)fulvalene (TMTSeF) in benzene (С6Н6) was studied. Comparison of experimental and calculated X-ray patterns showed that in the investigated single crystals of [(C70)x+(С60)y]· TMTSeF·2(C6H6) (х+у=3) (1) С70 and C60 fullerens are co-crystallized. IR spectral data and electroconductivity of 1 indicate the absence of the charge transfer on fullerene molecule for complexes under study.

References

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Published
2018-07-17
How to Cite
Blagov, M. A., Spitsina, N. G., & Konovalikhin, S. V. (2018). CO-CRYSTALLIZATION OF C60 AND С70 FULLERENES IN CRYSTAL-SOLVATE [(C70)X+(С60)Y]• TMTSeF•2(C6H6) (х+у=3). ChemChemTech, 59(9), 21-24. https://doi.org/10.6060/tcct.20165909.3y
Section
CHEMISTRY (inorganic, organic, analytical, physical, colloid and high-molecular compounds)