РАВНОВЕСИЕ, КИНЕТИКА И ТЕРМОДИНАМИЧЕСКИЕ ИССЛЕДОВАНИЯ БИОСОРБЦИИ КОНГО КРАСНОГО КРАСИТЕЛЯ БИОМАССОЙ SERRATIA MARCESCENS MM06
Аннотация
Красители представляют собой экологические риски с канцерогенными эффектами, которые ощущаются во всем мире, в том числе в Малайзии. Загрязнение воды происходит из различных источников, таких как производственные компании, исследовательские и медицинские центры. Целью исследования является изучение биосорбции красителя Конго красный (CR) бактериальной биомассой для промышленного применения. Двенадцать различных видов бактерий были протестированы на CR. Он проверяет и оптимизирует бактериальную сорбцию с использованием однофакторной (OFAT), он исследует инфракрасную Фурье-спектроскопию (FTIR), сканирующий электронный микроскоп (SEM), кинетические и равновесные модели и термодинамику. Штамм Serratia marcescens MM06 удалил больше всего красителя среди 12 бактериальных изолятов. Биомассу инкубировали с красителем 100 ppm, затем центрифугировали и измеряли при 507 нм. Оптимальными условиями после OFAT были 25°C, pH 7,0, перемешивание 125 об/мин, 20 мин, концентрация красителя 90 мг/л и дозировка абсорбента 0,94 г. FTIR и SEM характеризовали биосорбцию. Нелинейная регрессия проанализировала изотермы и кинетику, выявив псевдовторой порядок и Ленгмюр как наилучшие соответствия. Параметры подобранных изотерм, а именно, Ленгмюра, Фрейндлиха, БЭТ, Sips, Фрица-Шлюндера IV и Фрица-Шлюндера V, составили 4,387657 мг/г, 3,750862 мг/г, 4,387657 мг/г, 2,800659 мг/г, 12,178957 мг/г, 2,557313 мг/г соответственно. Параметры термодинамической свободной энергии Гиббса (DG), энтальпии (DH) и энтропии (DS) модификации указывают на экзотермические и спонтанные процессы. Serratia marcescens MM06 оказался эффективным для удаления красителя CR из сточных вод.
Для цитирования:
Сабо И.А., Маногаран М., Ясид Н.А., Отман А.Р., Абд Шукор М.Ю. Равновесие, кинетика и термодинамические исследования биосорбции конго красного красителя Биомассой Serratia marcescens MM06. Изв. вузов. Химия и хим. технология. 2026. Т. 69. Вып. 3. С. 117-127 DOI: 10.6060/ivkkt.20266903.6346.
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