ПОЛИМЕРНЫЕ БАРЬЕРНЫЕ МАТЕРИАЛЫ, ПРИМЕНЯЕМЫЕ В ГИБКОЙ УПАКОВКЕ
Аннотация
Создание барьерного слоя, препятствующего проникновению кислорода, важно в современных полимерных материалах, особенно при использовании их в гибкой упаковке. Кислород, проникающий через упаковку, может приводить к окислению и деструкции упакованной продукции, а также способствовать развитию микроорганизмов. Такие свойства особенно важны в пищевой, фармацевтической и электротехнической промышленности. В данном обзоре описаны основные барьерные материалы, применяемые для защиты от кислорода в гибкой упаковке. Для каждого из материалов представлены его характеристики, методы и способы получения, основные преимущества и недостатки. Описаны такие среднебарьерные материалы, как полиэтилентерефталат, полиамиды, поливинилиденхлорид. Полиэтилентерефталат, обладая такими преимуществами, как распространенность и легкая вторичная переработка, все же обладает таким недостатком, как дороговизна. Нейлоны являются удобным материалом для создания среднебарьерных покрытий. Ограничивает применение полиамидов их высокий уровень водопоглощения и дороговизна материала. Поливинилиденхлорид надо с осторожностью применять для упаковки пищевых продуктов, несмотря на его высокие барьерные свойства. Для создания высокобарьерной упаковки можно применять такие материалы, как поливиниловый и этиленвиниловый спирты, а также органо-неорганические гибридные полимеры. Описанные спирты обладают низкой кислородопроницаемостью, при этом их главный недостаток – гидрофильность, которая существенно ограничивает их применение. Гибридные кремнийорганические полимеры могут использоваться для создания ультравысокого барьера, особенно в комбинации со слоем оксида кремния или оксида алюминия. В обзоре показано, что описанные барьерные материалы могут являться удобной и экологичной альтернативой металлизации и фольге.
Для цитирования:
Липин К.В., Муратов И.И., Гильфанов С.А., Тептина А.И., Агафонова А.Р. Полимерные барьерные материалы, применяемые в гибкой упаковке. Изв. вузов. Химия и хим. технология. 2025. Т. 68. Вып. 12. С. 6-22. DOI: 10.6060/ivkkt.20256812.7240.
Литература
Lee D.S., Robertson G.L. Interactive influence of decision criteria, packaging film, storage temperature and humidity on shelf life of packaged dried vegetables. Food Packag. Shelf Life. 2021. V. 28. P. 100674. DOI: 10.1016/j.fpsl.2021.100674.
Gaikwad K.K., Singh S., Lee Y.S. Oxygen scavenging films in food packaging. Environ. Chem. Lett. 2018. V. 16. P. 523-538. DOI: 10.1007/s10311-018-0705-z.
Sid S., Mor R.S., Kishore A., Sharanagat V.S. Biosourced polymers as alternatives to conventional food packaging materials: A review. Trends Food Sci. Technol. 2021. V. 115. P. 87-104. DOI: 10.1016/j.tifs.2021.06.026.
Lamberti M., Escher F. Aluminium foil as a food packaging material in comparison with other materials. Food Rev. Int. 2007. V. 23. P. 407-433. DOI: 10.1080/87559120701593830.
Geueke B., Groh K., Muncke J. Food packaging in the circular economy: Overview of chemical safety aspects for commonly used materials. J. Clean Prod. 2018. V. 193. P. 491-505. DOI: 10.1016/j.jclepro.2018.05.005.
Silva N., Pålsson H. Industrial packaging and its impact on sustainability and circular economy: A systematic literature review. J. Clean Prod. 2022. V. 333. P. 130165. DOI: 10.1016/j.jclepro.2021.130165.
Marangoni Júnior L., Coltro L., Dantas F.B.H., Vieira R.P. Research on Food Packaging and Storage. Coatings. 2022. V. 12. P. 1714. DOI: 10.3390/coatings12111714.
Lase I.S., Bashirgonbadi A., van Rhijn F. Material flow analysis and recycling performance of an improved mechanical recycling process for postconsumer flexible plastics. Waste Manag. 2022. V. 153. P. 249-263. DOI: 10.1016/j.wasman.2022.09.002.
Marangoni Júnior L., Ito D., Ribeiro S.M.L., Silva M.G. da, Alves R.M.V. Stability of β-carotene rich sweet potato chips packed in different packaging systems. LWT. 2018. V. 92. P. 442-450. DOI: 10.1016/j.lwt.2018.02.066.
Dey A., Neogi S. Oxygen scavengers for food packaging applications: A review. Trends Food Sci. Technol. 2019. V. 90. P. 26-34. DOI: 10.1016/j.tifs.2019.05.013.
Yildirim S., Röcker B., Rüegg N., Lohwasser W. Devel-opment of Palladium-based Oxygen Scavenger: Optimization of Substrate and Palladium Layer Thickness. Pack. Technol. Sci. 2015. V. 28. P. 710-718. DOI: 10.1002/pts.2134.
Faas N., Röcker B., Smrke S., Yeretzian C., Yildirim S. Prevention of lipid oxidation in linseed oil using a palladium-based oxygen scavenging film. Food Packag. Shelf Life. 2020. V. 24. P. 100488. DOI: 10.1016/j.fpsl.2020.100488.
Emmert K., Amberg-Schwab S., Braca F., Bazzichi A., Cecchi A., Somorowsky F. BioORMOCER® – compostable functional barrier coatings for food packaging. Polymers. 2021. V. 13. P. 1257. DOI: 10.3390/polym13081257.
Amberg-Schwab S. Functional Barrier Coatings on the Basis of Hybrid Polymers. Handbook of Sol-Gel Science and Technology. 2016. P. 1-21. DOI: 10.1007/978-3-319-19454-7_72-1.
Tyagi P., Salem K.S., Hubbe M.A., Pal L. Advances in barrier coatings and film technologies for achieving sustainable packaging of food products – A review. Trends Food Sci. Technol. 2021. V. 115. P. 461-485. DOI: 10.1016/j.tifs.2021.06.036.
Sivalingam V., Jayaraj J., Paul S.H.J. Measuring flow rate and purity in portable oxygen concentrators. Bul. Natl. Res. Cent. 2024. V. 48. P. 58. DOI: 10.1186/s42269-024-01209-y.
Nisticò R. Polyethylene terephthalate (PET) in the packaging industry. Polym. Test. 2020. V. 90. P. 106707. DOI: 10.1016/j.polymertesting.2020.106707.
Panowicz R., Konarzewski M., Durejko T. Properties of polyethylene terephthalate (Pet) after thermo-oxidative aging. Materials. 2021. V. 14. P. 3833. DOI: 10.3390/ma14143833.
Jaime S.B.M., Alves R.M.V., Bócoli P.F.J. Moisture and oxygen barrier properties of glass, PET and HDPE bottles for pharmaceutical products. J. Drug Deliv. Sci. Technol. 2022. V. 71. P. 9. DOI: 10.1016/j.jddst.2022.103330.
Sato K., Sprengel W. Element-specific study of local segmental dynamics of polyethylene terephthalate upon physical aging. J. Chem. Phys. 2012. V. 137. P. 104906. DOI: 10.1063/1.4751553.
Crippa M., Morico B. PET depolymerization: A novel process for plastic waste chemical recycling. Stud. Surf. Sci. Catal. 2019. V. 179. P. 215-229. DOI: 10.1016/B978-0-444-64337-7.00012-4.
Dang Y., Luo X., Wang F., Li Y. Valueadded conversion of waste cooking oil and post-consumer PET bottles into biodiesel and polyurethane foams. Waste Manag. 2016. V. 52. P. 360-366. DOI: 10.1016/j.wasman.2016.03.054.
Nait-Ali L.K., Colin X., Bergeret A. Kinetic analysis and modelling of PET macromolecular changes during its mechanical recycling by extrusion. Polym. Degrad. Stab. 2011. V. 96. P. 236-246. DOI: 10.1016/j.polymdegradstab.2010.11.004.
Qin Y., Qu M., Kaschta J., Schubert D.W. Comparing recycled and virgin poly (ethylene terephthalate) melt-spun fibres. Polym. Test. 2018. V. 72. P. 364-371. DOI: 10.1016/j.polymertesting.2018.10.028.
Brems A., Baeyens J., Vandecasteele C., Dewil R. Poly-meric cracking of waste polyethylene terephthalate to chemi-cals and energy. J. Air. Waste. Manag. Assoc. 2011. V. 61. P. 721-731. DOI: 10.3155/1047-3289.61.7.721.
Pang J., Zheng M., Sun R., Wang A., Wang X., Zhang T. Synthesis of ethylene glycol and terephthalic acid from biomass for producing PET. Green Chem. 2016. V. 18. P. 342-359. DOI: 10.1039/c5gc01771h.
Han Z., Rong L., Wu J., Zhang L., Wang Z., Ding K. Catalytic hydrogenation of cyclic carbonates: A practical ap-proach from CO2 and epoxides to methanol and diols. Angew. Chem. Int. Ed. Engl. 2012. V. 51. P. 13218-13222. DOI: 10.1002/anie.201207781.
Dong K., Elangovan S., Sang R. Selective catalytic two-step process for ethylene glycol from carbon monoxide. Nat. Commun. 2016. V. 7. P. 12075. DOI: 10.1038/ncomms12075.
Luo N., Ji Y., Mao Y., Zhang B. Syngas-based mono ethylene glycol synthesis in Pujing Chemical. Appl. Petrochem. Res. 2012. V. 2. P. 23-26. DOI: 10.1007/s13203-012-0012-8.
Gaffney A.M., Leonard J.J., Sofranko J.A., Sun H.N. Heterogeneous catalyst for alcohol oxycarbonylation to dialkyl oxalates. J. Catal. 1984. V. 90. P. 261-269. DOI: 10.1016/0021-9517(84)90254-9.
Li M., Ruddy T., Fahey D., Busch D.H., Subramaniam B. Terephthalic acid production via greener spray process: Comparative economic and environmental impact assessments with midcentury process. ACS Sustain Chem. Eng. 2014. V. 2. P. 823-835. DOI: 10.1021/sc4004778.
Tomás R.A.F., Bordado J.C.M., Gomes J.F.P. Pxylene oxidation to terephthalic acid: A literature review oriented toward process optimization and development. Chem. Rev. 2013. V. 113. P. 7421-7469. DOI: 10.1021/cr300298j.
Liu T., Gu X., Wang J., Feng L. Modeling and analysis of new reactor concepts for poly(ethylene terephthalate) esterification process. Chem. Eng. Process. 2019. V. 135. P. 217-226. DOI: 10.1016/j.cep.2018.12.002.
De Vos L., Van de Voorde B., Van Daele L., Dubruel P., Van Vlierberghe S. Poly(alkylene terephthalate)s: From current developments in synthetic strategies towards applications. Eur. Polym J. 2021. V. 161. P. 110840. DOI: 10.1016/j.eurpolymj.2021.110840.
Adibi A., Trinh B.M., Mekonnen T.H. Recent progress in sustainable barrier paper coating for food packaging applications. Prog. Org. Coatings. 2023. V. 181. P. 107566. DOI: 10.1016/j.porgcoat.2023.107566.
Yun S., Jung J., Jun S., Jeong J., Moon Y.H., Kim J.H. Constitutive and Fracture Modeling of Biaxially Oriented Polyethylene Terephthalate Film and Its Application to Polymer-Coated Sheet Metal Forming. J. Manuf. Sci. Eng. Trans. ASME. 2021. V. 143. P. 1-22. DOI: 10.1115/1.4049190.
Chevalier L., Luo Y.M., Nguyen T.T., Attar H. Multiscale framework for estimation of induced elastic properties of Poly ethylene terephthalate after biaxial elongation. Mech. Mater. 2024. V. 192. P. 104962. DOI: 10.1016/j.mechmat.2024.104962.
Hornak J., Kadlec P., Kopřiva J., Polanský R. Dielectric, structural and mechanical properties of thermally aged biaxially oriented polymeric substrates for flexible electronics. Polym. Degrad. Stab. 2022. V. 199. P. 109906. DOI: 10.1016/j.polymdegradstab.2022.109906.
Burgos Pintos P., Sanz de León A., Molina S.I. Large format additive manufacturing of polyethylene terephthalate (PET) by material extrusion. Addit. Manuf. 2024. V. 79. P. 103908. DOI: 10.1016/j.addma.2023.103908.
Dombre C., Marais S., Chappey C., Lixon-Buquet C., Chalier P. The behaviour of wine aroma compounds related to structure and barrier properties of virgin, recycled and active PET membranes. J. Memb. Sci. 2014. V. 463. P. 215-225. DOI: 10.1016/j.memsci.2014.03.066.
Liu R.Y.F., Hu Y.S., Schiraldi D.A., Hiltner A., Baer E. Crystallinity and oxygen transport properties of PET bottle walls. J. Appl. Polym. Sci. 2004. V. 94. P. 671-677. DOI: 10.1002/app.20905.
Winnacker M. Polyamides and their functionalization: Recent concepts for their applications as biomaterials. Biomater. Sci. 2017. V. 5. P. 230-1235. DOI: 10.1039/c7bm00160f.
Ding Y., Qiu Y., Cai K. High performance n-type Ag 2 Se film on nylon membrane for flexible thermoelectric power generator. Nat. Commun. 2019. V. 10. P. 841. DOI: 10.1038/s41467-019-08835-5.
Shakiba M., Rezvani Ghomi E., Khosravi F. Nylon – A material introduction and overview for biomedical applications. Polym. Adv. Technol. 2021. V. 32. P. 3368-3383. DOI: 10.1002/pat.5372.
Winnacker M., Rieger B. Biobased Polyamides: Recent Advances in Basic and Applied Research. Macromol. Rapid Commun. 2016. V. 37. P. 1391-1413. DOI: 10.1002/marc.201600181.
Coates G.W., Getzler Y.D.Y.L. Chemical recycling to monomer for an ideal, circular polymer economy. Nat. Rev. Mater. 2020. V. 5. P. 3270-3276. DOI: 10.1038/s41578-020-0190-4.
Winnacker M., Beringer A.J.G., Gronauer T.F. Polyam-ide/PEG Blends as Biocompatible Biomaterials for the Convenient Regulation of Cell Adhesion and Growth. Macromol. Rapid Commun. 2019. V. 40. P. e1900091. DOI: 10.1002/marc.201900091.
Bigham A., Foroughi F., Rezvani Ghomi E., Rafienia M., Neisiany R.E., Ramakrishna S. The journey of multifunctional bone scaffolds fabricated from traditional toward modern techniques. Bio-Des. Manuf. 2020. V. 3. P. 281-306. DOI: 10.1007/s42242-020-00094-4.
Aparna S., Purnima D., Adusumalli R.B. Review on Various Compatibilizers and its Effect on Mechanical Properties of Compatibilized Nylon Blends. Polym – Plast. Technol. Eng. 2017. V. 56. P. 617-634. DOI: 10.1080/03602559.2016.1233280.
Hu R., Li M., Shen T. A sustainable process to 100% biobased nylons integrated chemical and biological conversion of lignocellulose. Green Energy Environ. 2024. V. 9. P. 390-402. DOI: 10.1016/j.gee.2022.11.004.
Nguyen T.N.M., Yoo D.Y., Kim J.J. Cementitious material reinforced by carbon nanotube-Nylon 66 hybrid nanofibers: Mechanical strength and microstructure analysis. Mater Today Commun. 2020. V. 23. P. 100845. DOI: 10.1016/j.mtcomm.2019.100845.
Nguyen T.N.M., Moon J., Kim J.J. Microstructure and mechanical properties of hardened cement paste including Nylon 66 nanofibers. Constr. Build. Mater. 2020. V. 232. P. 117134. DOI: 10.1016/j.conbuildmat.2019.117134.
Owlia E., Shaikhzadeh Najar S., Tavana R. Experimental and macro finite element modeling studies on conformability behavior of woven nylon 66 composite reinforcement. J. Text. Inst. 2020. V. 111. P. 1-8. DOI: 10.1080/00405000.2019.1670923.
Kim D.K., Lee A.S., Baek B.K., Song K.H., Hong S.M., Koo C.M. PPE/Nylon 66 Blends with High Mechanical Toughness and Flame Retardancy. Macromol. Res. 2020. V. 28. P. 1-7. DOI: 10.1007/s13233-020-8022-3.
Choudhari D.S., Kakhandki V.J. Comprehensive study and analysis of mechanical properties of chopped carbon fibre reinforced nylon 66 composite materials. Mater. Today: Pro-ceed. 2020. V. 44. P. 4596-4601. DOI: 10.1016/j.matpr.2020.10.828.
Xiang C., Etrick N.R., Frey M.W., Norris E.J., Coats J.R. Structure and properties of polyamide fabrics with insectrepellent functionality by electrospinning and oxygen plasma-treated surface coating. Polymers. 2020. V. 12. P. 2196. DOI: 10.3390/POLYM12102196.
Zhou L.Y., Fu J., He Y. A Review of 3D Printing Technologies for Soft Polymer Materials. Adv. Funct. Mater. 2020. V. 30. P. 2000187. DOI: 10.1002/adfm.202000187.
Ghomi E.R., Khosravi F., Mossayebi Z. The Flame Retardancy of Polyethylene Composites: From Fundamental Con-cepts to Nanocomposites. Molecules. 2020. V. 25. P. 5157. DOI: 10.3390/molecules25215157.
Sato H., Ohtani H., Harada R., Tsuge S., Kato M., Usuki A. Polymer/silicate interaction in nylon 6-clay hybrid studied by temperature programmed pyrolysis techniques. Polym. J. 2006. V. 38. P. 171-177. DOI: 10.1295/polymj.38.171.
Ali M.G., Mousa H.M., Blaudez F. Dual nanofiber scaffolds composed of polyurethane- gelatin/nylon 6- gelatin for bone tissue engineering. Colloids Surfaces A Physicochem. Eng. Asp. 2020. V. 597. P. 124817. DOI: 10.1016/j.colsurfa.2020.124817.
Castelvetro V., Corti A., Ceccarini A., Petri A., Vinciguerra V. Nylon 6 and nylon 6,6 micro- and nanoplastics: A first example of their accurate quantification, along with polyester (PET), in wastewater treatment plant sludges. J. Hazard Mater. 2021. V. 407. P. 124364. DOI: 10.1016/j.jhazmat.2020.124364.
Krishna S., Patel C.M. Computational and experimental study of mechanical properties of Nylon 6 nanocomposites reinforced with nanomilled cellulose. Mech. Mater. 2020. V. 143. P. 103318. DOI: 10.1016/j.mechmat.2020.103318.
Ma Y., Jin S., Yokozeki T. Effect of hot water on the mechanical performance of unidirectional carbon fiber-reinforced nylon 6 composites. Compos. Sci. Technol. 2020. V. 200. P. 108426. DOI: 10.1016/j.compscitech.2020.108426.
Tokiwa Y., Calabia B.P., Ugwu C.U., Aiba S. Biodegrada-bility of plastics. Int. J. Mol. Sci. 2009. V. 10. P. 3722-3742. DOI: 10.3390/ijms10093722.
Liu F., Wang Z., Liu D., Li J. Curing of diglycidyl ether of bisphenol-A epoxy resin using a poly(aryl ether ketone) bearing pendant carboxyl groups as macromolecular curing agent. Polym. Int. 2009. V. 58. P. 912-918. DOI: 10.1002/pi.2612.
Jing W., Hui C., Qiong W., Hongbo L., Zhanjun L. Surface modification of carbon fibers and the selective laser sin-tering of modified carbon fiber/nylon 12 composite powder. Mater. Des. 2017. V. 116. P. 253-260. DOI: 10.1016/j.matdes.2016.12.037.
Mostafa K.G., Montemagno C., Qureshi A.J. Strength to cost ratio analysis of FDM Nylon 12 3D Printed Parts. Procedia Manuf. 2018. V. 26. P. 753-762. DOI: 10.1016/ j.promfg.2018.07.086.
Hui C., Qingyu C., Jing W., Xiaohong X., Hongbo L., Zhanjun L. Interfacial enhancement of carbon fiber/nylon 12 composites by grafting nylon 6 to the surface of carbon fiber. Appl. Surf. Sci. 2018. V. 441. P. 538-545. DOI: 10.1016/j.apsusc.2018.01.158.
Ryšánek P., Malý M., Čapková P. Antibacterial modification of nylon-6 nanofibers: structure, properties and antibacterial activity. J. Polym. Res. 2017. V. 24. P. 208. DOI: 10.1007/s10965-017-1365-6.
Singh R., Kumar R., Ranjan N., Penna R., Fraternali F. On the recyclability of polyamide for sustainable composite structures in civil engineering. Compos. Struct. 2018. V. 184. P. 704-713. DOI: 10.1016/j.compstruct.2017.10.036.
Guo X., Liu L., Feng H., Li D., Xia Z., Yang R. Flame Retardancy of Nylon 6 Fibers: A Review. Polymers. 2023. V. 15. P. 2161. DOI: 10.3390/polym15092161.
Ferrari D., Sanguineti A., Mirenda M., Vanderveken Y. Compatibility of polyvinylidene chloride with mechanical recycling of polyolefins. Prog. Rubber, Plast. Recycl. Technol. 2023. V. 39. P. 264-280. DOI: 10.1177/14777606231152268.
Lewandowski K., Skórczewska K. A Brief Review of Poly(Vinyl Chloride) (PVC) Recycling. Polymers. 2022. V. 14. P. 3035. DOI: 10.3390/polym14153035.
Huang J., Li X., Zeng G., Cheng X., Tong H., Wang D. Thermal decomposition mechanisms of poly(vinyl chloride): A computational study. Waste Manag. 2018. V. 76. P. 483-496. DOI: 10.1016/j.wasman.2018.03.033.
Roosen M., Mys N., Kusenberg M. Detailed Analysis of the Composition of Selected Plastic Packaging Waste Products and Its Implications for Mechanical and Thermochemical Recycling. Environ. Sci. Technol. 2020. V. 54. P. 13282-13293. DOI: 10.1021/acs.est.0c03371.
Veksha A., Giannis A., Oh W. Da, Chang V.W.C., Lisak G. Upgrading of non-condensable pyrolysis gas from mixed plastics through catalytic decomposition and dechlorination. Fuel Process Technol. 2018. V. 170. P. 13-20. DOI: 10.1016/j.fuproc.2017.10.019.
Ferrari D., Radice S., Sciarrillo V. PVDC multilayer films: Chemical recycling by means of catalytic conversion into aromatics (BTX). Sustain. Chem. Environ. 2023. V. 2. P. 100010. DOI: 10.1016/j.scenv.2023.100010.
Radice S., Ferrari D., Millefanti S., Gregori M. PVDC multilayer sorting challenge: A spectroscopy study and on field application. Sustain. Chem. Environ. 2025. V. 9. P. 100188. DOI: 10.1016/J.SCENV.2024.100188.
Ait-Touchente Z., Khellaf M., Raffin G., Lebaz N., Elaissari A. Recent advances in polyvinyl chloride (PVC) re-cycling. Polym. Adv. Technol. 2024. V. 35. P. hal-04267777f. DOI: 10.1002/pat.6228.
Zhao F., Yin Y., Zhang D. Preparation and characterization of novel thermal-stable vinylidene chloride-methyl acrylate-glycidyl methacrylate copolymer. Int. J. Polym. Anal. Charact. 2017. V. 22. P. 338-347. DOI: 10.1080/1023666X.2017.1295596.
Liu Y., Yang L., Zhang R. Preparation and properties of thermal yellowing resistant polyvinylidene chloride resin. Adv. Compos. Hybrid Mater. 2025. V. 8. P. 15. DOI: 10.1007/s42114-024-01092-1.
Li J., Hong C., Zhang H. Fabrication of self-cross-linking silicified polyvinylidene chloride emulsions with core-shell structure and its film properties. Polym. Bull. 2024. V. 81. P. 1-23. DOI: 10.1007/s00289-023-04779-5.
Liu M., Li J., Hong C. Synthesis and characterization of organosilicon functionalized water-based polyvinylidene chloride emulsion with coreshell structure. Mater. Today Commun. 2024. V. 39. P. 108548. DOI: 10.1016/j.mtcomm.2024.108548.
Lin Z.Z., Wang Y., Wu Y., Yang X.B., Chen Y., Li H.C. Sensitive roomtemperature phosphorescence for luminometric and visual monitoring of the dynamic evolution of acrylate-vinylidene chloride copolymers. Spectrochim. Acta – Part A Mol. Biomol. Spectrosc. 2023. V. 286. P. 122016. DOI: 10.1016/j.saa.2022.122016.
Wang L., Yi J.M., Zhang D.Q., Wang M., Peng X.H. Ef-fect of CaSt2/ESO thermal stabilizers on the preparation, thermal stability, and thermal stability mechanism of selfmade vinylidene chloridemethyl acrylate copolymer resin film. J. Appl. Polym. Sci. 2022. V. 139. P. e52688. DOI: 10.1002/app.52688.
Okada T., Sutoh S., Sejima K., Tomohara H., Mishima S. A useful method for thorough dehydrochlorination of Poly(vinylidene chloride-co-vinyl chloride) using Zinc(II) oxide. Polym. Degrad Stab. 2020. V. 171. P. 109040. DOI: 10.1016/j.polymdegradstab.2019.109040.
Xiao X., Zeng Z., Xiao S. Behavior and products of mecha-no-chemical dechlorination of polyvinyl chloride and poly (vi-nylidene chloride). J. Hazard Mater. 2008. V. 151. P. 118-124. DOI: 10.1016/j.jhazmat.2007.05.067.
Wang X., Song M., Liu S., Wu S., Thu A.M. Analysis of phthalate plasticizer migration from PVDC packaging materials to food simulants using molecular dynamics simulations and artificial neural network. Food Chem. 2020. V. 317. P. 126465. DOI: 10.1016/j.foodchem.2020.126465.
Garnier J., Dufils P.E., Vinas J., Vanderveken Y., Van Herk A., Lacroix-Desmazes P. Synthesis of poly(vinylidene chloride)-based composite latexes by emulsion polymerization from epoxy functional seeds for improved thermal stability. Polym. Degrad. Stab. 2012. V. 97. P. 170-177. DOI: 10.1016/j.polymdegradstab.2011.10.019.
Akkamma M.B., Lobo B. Optical properties of UV-C irra-diated polyvinylidene chloride films. Radiat. Phys. Chem. 2023. V. 212. P. 111182. DOI: 10.1016/j.radphyschem.2023.111182.
Wang Y., Li C., Zhang X. Poly(vinylidene chlo-ride)/Poly(chlorotrifluoroethylene-co-acrylates) Composite Latex Coating Cured at Room Temperature Showing an Ex-cellent Corrosion Resistance. Chem. Select. 2020. V. 5. P. 6278-6284. DOI: 10.1002/slct.202000651.
Liu J., Goss J., Calverley T. Self-standing permselective CMS membrane from melt extruded PVDC. J. Memb. Sci. 2020. V. 615. P. 118554. DOI: 10.1016/j.memsci.2020.118554.
Delafresnaye L., Dugas P.Y., Dufils P.E. Synthesis of clayarmored poly(vinylidene chloride-: Co -methyl acrylate) latexes by Pickering emulsion polymerization and their filmforming properties. Polym. Chem. 2017. V. 8. P. 6217-6232. DOI: 10.1039/c7py00902j.
Rodrigues J.B., Brunelli K., De Luca Sarantopoulos C.I.G., De Oliveira L.M. Properties of barrier shrink bags made with EVOH and polyamide for fresh beef meat preservation. Polimeros. 2018. V. 28. P. 1-6. DOI: 10.1590/0104-1428.04516.
Li Z., Tian C., Yu S., Lin X., Liang S., Wang J. Construction of durable polyurea/polyvinylidene chloride composite film with high water vapor barrier property. Thin Solid Films. 2022. V. 752. P. 139253. DOI: 10.1016/j.tsf.2022.139253.
Liu Y., Zhu Y., Yuan S. Crystalline polyvinylidene chloride embedded in epoxy composite coating for oxygen gas barrier and anticorrosion. Chem. Eng. J. 2023. V. 474. P. 145848. DOI: 10.1016/j.cej.2023.145848.
Abdullah Z.W., Dong Y., Davies I.J., Barbhuiya S. PVA, PVA Blends, and Their Nanocomposites for Biodegradable Packaging Application. Polym. – Plast. Technol. Eng. 2017. V. 56. P. 1307-1344. DOI: 10.1080/03602559.2016.1275684.
Ye M., Mohanty P., Ghosh G. Morphology and properties of poly vinyl alcohol (PVA) scaffolds: Impact of process variables. Mater. Sci. Eng. C. 2014. V. 42. P. 289-294. DOI: 10.1016/j.msec.2014.05.029.
Saini I., Sharma A., Dhiman R., Aggarwal S., Ram S., Sharma P.K. Grafted SiC nanocrystals: For enhanced optical, electrical and mechanical properties of polyvinyl alcohol. J. Al-loys. Compd. 2017. V. 714. P. 172-180. DOI: 10.1016/j.jallcom.2017.04.183.
Aslam M., Kalyar M.A., Raza Z.A. Fabrication of reduced graphene oxide nanosheets doped PVA composite films for tailoring their opto-mechanical properties. Appl. Phys. A Ma-ter. Sci. Process. 2017. V. 123. P. 424. DOI: 10.1007/s00339-017-1035-x.
Ben Halima N. Poly(vinyl alcohol): Review of its promising applications and insights into biodegradation. RSC Adv. 2016. V. 6. P. 9823-39832. DOI: 10.1039/c6ra05742j.
Aslam M., Kalyar M.A., Raza Z.A. Polyvinyl alcohol: A review of research status and use of polyvinyl alcohol based nanocomposites. Polym. Eng. Sci. 2018. V. 58. P. 2119-2132. DOI: 10.1002/pen.24855.
Gaaz T.S., Sulong A.B., Akhtar M.N. Properties and applications of polyvinyl alcohol, halloysite nanotubes and their nanocomposites. Molecules. 2015. V. 20. P. 22833-22847. DOI: 10.3390/molecules201219884.
Julinová M., Vaňharová L., Jurča M. Water-soluble polymeric xenobiotics – Polyvinyl alcohol and polyvinylpyrrolidon – And potential solutions to environmental issues: A brief review. J. Environ. Manage. 2018. V. 228. P. 213-222. DOI: 10.1016/j.jenvman.2018.09.010.
Kawai F., Hu X. Biochemistry of microbial polyvinyl alcohol degradation. Appl. Microbiol. Biotechnol. 2009. V. 84. P. 227-237. DOI: 10.1007/s00253-009-2113-6.
Apicella A., Barbato A., Garofalo E., Incarnato L., Scarfato P. Effect of PVOH/PLA + Wax Coatings on Physi-cal and Functional Properties of Biodegradable Food Packag-ing Films. Polymers. 2022. V. 14. P. 935. DOI: 10.3390/polym14050935.
Chuaponpat N., Ueda T., Ishigami A., Kurose T., Ito H. Morphology, thermal and mechanical properties of cocontinuous porous structure of PLA/PVA blends by phase separation. Polymers. 2020. V. 12. P. 1083. DOI: 10.3390/POLYM12051083.
Shi B., Wideman G., Wang J.H. Improving the processability of water-soluble films based on filled thermoplastic polyvinyl alcohol. Int. Polym. Process. 2012. V. 27. P. 231-236. DOI: 10.3139/217.2517.
Suganthi S., Vignesh S., Kalyana Sundar J., Raj V. Fabrication of PVA polymer films with improved antibacterial activity by finetuning via organic acids for food packaging applications. Appl. Water Sci. 2020. V. 10. P. 100. DOI: 10.1007/s13201-020-1162-y.
Leneveu-Jenvrin C., Apicella A., Bradley K. Effects of maturity level, steam treatment, or active packaging to maintain the quality of minimally processed mango (Mangifera indica cv. José). J. Food Process Preserv. 2021. V. 45. P. e15600. DOI: 10.1111/jfpp.15600.
Apicella A., Scarfato P., Di Maio L., Incarnato L. Oxygen absorption data of multilayer oxygen scavenger-polyester films with different layouts. Data Br. 2018. V. 19. P. 1530-1536. DOI: 10.1016/j.dib.2018.06.024.
Florit F., Fiorati A., Ghisoni F., Pozzoli G., Rota R., De Nardo L. Development of a generalised equilibrium modified atmosphere model and its application to the Taleggio cheese. J. Food. Eng. 2022. V. 315. P. 110765. DOI: 10.1016/j.jfoodeng.2021.110765.
Shen Z., Kwon S., Oh K., Abhari A.R., Lee H.L. Facile fabrication of hydrophobic cellulosic paper with good barrier properties via PVA/AKD dispersion coating. Nord. Pulp Pap Res. J. 2019. P. 516-524. DOI: 10.1515/npprj-2019-0040.
Yue S., Wang S., Han D. Polyvinyl Alcohol/Montmorillonite Nanocomposite Coated Biodegradable Films with Outstanding Barrier Properties. ES Mater. Manuf. 2023. V. 20. P. 834. DOI: 10.30919/esmm5f834.
Anukiruthika T., Sethupathy P., Wilson A., Kashampur K., Moses J.A., Anandharamakrishnan C. Multilayer packaging: Advances in preparation techniques and emerging food applications. Compr. Rev. Food Sci. Food Saf. 2020. V. 19. P. 1156-1186. DOI: 10.1111/1541-4337.12556.
Andrade J., González-Martínez C., Chiralt A. Antimicrobial PLA-PVA multilayer films containing phenolic compounds. Food Chem. 2022. V. 375. P. 131861. DOI: 10.1016/j.foodchem.2021.131861.
Ullah S., Hashmi M., Shi J., Kim I.S. Fabrication of Electrospun PVA/Zein/Gelatin Based Active Packaging for Quality Maintenance of Different Food Items. Polymers. 2023. V. 15. P. 2538. DOI: 10.3390/polym15112538.
Ge L., Zhao Y.S., Mo T., Li J.R., Li P. Immobilization of glucose oxidase in electrospun nanofibrous membranes for food preservation. Food Control. 2012. V. 26. P. 188-193. DOI: 10.1016/j.foodcont.2012.01.022.
Suhag A., Biswas K., Singh S., Kulshreshtha A. Crosslinking effect on polyvinyl alcohol resin for barrier properties of barrier biaxial orientation films. Prog. Org. Coatings. 2022. V. 163. P. 106662. DOI: 10.1016/j.porgcoat.2021.106662.
Pan Q., Zhou C., Yang Z. Preparation and characterization of functionalized chitosan/polyvinyl alcohol composite films incorporated with cinnamon essential oil as an active packag-ing material. Int. J. Biol. Macromol. 2023. V. 235. P. 123914. DOI: 10.1016/j.ijbiomac.2023.123914.
Nguyen S. Van, Lee B.K. Multifunctional nanocomposite based on polyvinyl alcohol, cellulose nanocrystals, titanium dioxide, and apple peel extract for food packaging. Int. J. Biol. Macromol. 2023. V. 227. P. 551-563. DOI: 10.1016/j.ijbiomac.2022.12.073.
Kim H., Panda P.K., Sadeghi K., Seo J. Poly (vinyl alcohol)/hydrothermally treated tannic acid composite films as sustainable antioxidant and barrier packaging materials. Prog. Org. Coatings. 2023. V. 174. P. 107305. DOI: 10.1016/j.porgcoat.2022.107305.
Gigante V., Panariello L., Coltelli M.B. Liquid and solid functional bio-based coatings. Polymers. 2021. V. 13. P. 3640. DOI: 10.3390/polym13213640.
Apicella A., Scarfato P., Di Maio L., Incarnato L. Sustainable Active PET Films by Functionalization With Antimicrobial Bio-Coatings. Front. Mater. 2019. V. 6. DOI: 10.3389/fmats.2019.00243.
Janjarasskul T., Tananuwong K., Phupoksakul T., Thaiphanit S. Fast dissolving, hermetically sealable, edible whey protein isolate-based films for instant food and/or dry ingredient pouches. LWT. 2020. V. 134. P. 110102. DOI: 10.1016/j.lwt.2020.110102.
Mesgari M., Aalami A.H., Sathyapalan T., Sahebkar A. A Comprehensive Review of the Development of Carbohydrate Macromolecules and Copper Oxide Nanocomposite Films in Food Nanopackaging. Bioinorg. Chem. Appl. 2022. V. 2022. DOI: 10.1155/2022/7557825.
Mokwena K.K., Tang J. Ethylene Vinyl Alcohol: A Review of Barrier Properties for Packaging Shelf Stable Foods. Crit. Rev. Food Sci. Nutr. 2012. V. 52. P. 640-650. DOI: 10.1080/10408398.2010.504903.
Hajinezhad S., Razavizadeh B.M., Niazmand R., Ghasemi I. Antimicrobial, mechanical, and physicochemical properties of ethylene vinyl alcohol (EVOH) extruded films blended with propolis. Int. J. Food Prop. 2020. V. 23. P. 2020-2032. DOI: 10.1080/10942912.2020.1840388.
Dargahi A., Runka J., Hammami A., Naguib H.E. High-Temperature Multilayer Composite Films of Polyethylene/Ethylene Vinyl Alcohol with Enhanced Flexural Moduli and Gas Barrier Properties. ACS Appl. Polym. Mater. 2024. V. 6. P. 9817-9828. DOI: 10.1021/acsapm.4c01666.
Zainal Abedin N.H., Schiessl S., Langowski H.C. Buckling Resistance and Its Effect on the Gas Barrier of Composite Coating Layers Based on Polyvinyl Alcohol and Montmorillonite. Coatings. 2024. V. 14. P. 1578. DOI: 10.3390/coatings14121578.
Prykhodko Y., Martin A., Oulyadi H., Marais S., Fatyeyeva K. Polymer EVA-OH membrane with improved water/gas separation performance: Influence of VAc/VOH repeating units ratio on membrane physical chemical properties. J. Memb Sci. 2023. V. 673. P. 121386. DOI: 10.1016/j.memsci.2023.121386.
He Y., Lao J., Ke H., Lu Y. Effect of composition and structure of ethylenevinyl acetate copolymer on its alcoholysis kinetics: A combined experimental and DFT study. Chem. Eng. J. 2023. V. 477. P. 146965. DOI: 10.1016/j.cej.2023.146965.
He Y., Zhang Z., Ke H., Lu Y. Microflow system for con-trolled synthesis of ethylene-vinyl acetate copolymers: Continuous copolymerization and kinetic study. Chem. Eng. J. 2023. V. 470. P. 143940. DOI: 10.1016/j.cej.2023.143940.
Shah Y.A., Bhatia S., Al-Harrasi A. Insights into recent innovations in barrier resistance of edible films for food pack-aging applications. Int. J. Biol. Macromol. 2024. V. 271. P. 132354. DOI: 10.1016/J.IJBIOMAC.2024.132354.
Kim J., Oh S., Cho S.M., Jun J., Kwak S. Oxygen barrier properties of polyketone/EVOH blend films and their resistance to moisture. J. Appl. Polym. Sci. 2020. V. 137. P. 49537. DOI: 10.1002/app.49537.
Salem K.S., Lubna M.M., Rahman A.M., Nurnabi M., Islam R., Khan M.A. The effect of multiwall carbon nano-tube additions on the thermo-mechanical, electrical, and mor-phological properties of gelatin-polyvinyl alcohol blend nano-composite. J. Compos. Mater. 2015. V. 49. P. 1379-1391. DOI: 10.1177/0021998314534704.
Sun M., Zhu S., Zhang C., Olah A., Baer E., Schiraldi D.A. HDPE/EVOH Multilayered, High Barrier Films for Flexible Organic Photovoltaic Device Packaging. ACS Appl. Polym. Mater. 2019. V. 1. P. 259-266. DOI: 10.1021/acsapm.8b00181.
Elhamnia M., Motlagh G.H., Jafari S.H. A multiple approach in determination of interfacial tension of biodegradable meltmixed PBAT/EVOH blends: Correlation of morphology, rheology and mechanical properties. Polym. Test. 2020. V. 82. P. 106301. DOI: 10.1016/j.polymertesting.2019.106301.
Deng P., Liu M., Zhang W., Sun J. Preparation and physical properties of enhanced radiation induced crosslinking of ethylenevinyl alcohol copolymer (EVOH). Nucl. Instruments Methods Phys. Res. Sect B Beam Interact with Mater. Atoms. 2007. V. 258. P. 357-361. DOI: 10.1016/j.nimb.2007.01.300.
Cabedo L., Lagarón J.M., Cava D., Saura J.J., Giménez E. The effect of ethylene content on the interaction between ethylenevinyl alcohol copolymers and water-II: Influence of water sorption on the mechanical properties of EVOH copolymers. Polym. Test. 2006. V. 25. P. 860-867. DOI: 10.1016/j.polymertesting.2006.04.012.
Chen L., Dong H., Pan W., Dai J., Dai X., Pan J. Poly (vinyl alcohol-co-ethylene) (EVOH) modified polymer inclu-sion membrane in heavy rare earths separation with advanced hydrophilicity and separation property. Chem. Eng. J. 2021. V. 426. P. 131305. DOI: 10.1016/j.cej.2021.131305.
Lasagabáster A., Abad M.J., Barral L., Ares A., Bouza R. Application of FTIR spectroscopy to determine transport properties and water-polymer interactions in polypropylene (PP)/poly(ethylene-co-vinyl alcohol) (EVOH) blend films: Ef-fect of poly(ethylene-co-vinyl alcohol) content and water ac-tivity. Polymer. 2009. V. 50. P. 2981-2989. DOI: 10.1016/j.polymer.2009.04.005.
Zhang G., Xu H., Macinnis K., Baer E. The structure-property relationships of LLDPE-EVOH blend films fabricated by multiplication extrusion. Polymer. 2015. V. 57. P. 117-124. DOI: 10.1016/j.polymer.2014.12.025.
Barros C., Carneiro O.S., Machado A.V. From multilayer LDPE/EVOH flexible film scraps to new multilayer films. Polymer. 2024. V. 314. P. 127695. P. 127695. DOI: 10.1016/J.POLYMER.2024.127695.
Azzaz C.M., Duncan M., Runka J., Hammami A., Naguib H., Lee P.C. Adhesion dynamics and interfacial be-havior at room and high temperatures of ethylene vinyl alcohol/polyethylene-grafted maleic anhydride composite multi-layer films obtained by co-extrusion. J. Manuf. Process. 2025. V. 136. P. 217-227. DOI: 10.1016/J.JMAPRO.2025.01.064.
Magnaghi L.R., Zanoni C., Alberti G., Quadrelli P., Biesuz R. Towards intelligent packaging: BCP-EVOH optode for milk freshness measurement. Talanta. 2022. V. 241. P. 123230. DOI: 10.1016/j.talanta.2022.123230.
Mateo E.M., Gómez J. V., Domínguez I. Impact of bioac-tive packaging systems based on EVOH films and essential oils in the control of aflatoxigenic fungi and aflatoxin production in maize. Int. J. Food Microbiol. 2017. V. 254. P. 36-46. DOI: 10.1016/J.IJFOODMICRO.2017.05.007.
López-De-Dicastillo C., Catalá R., Gavara R., Hernández-Muñoz P. Food applications of active packaging EVOH films containing cyclodextrins for the preferential scavenging of un-desirable compounds. J. Food Eng. 2011. V. 104. P. 380-386. DOI: 10.1016/J.JFOODENG.2010.12.033.
López-Rubio A., Lagarón J.M., Hernández-Muñoz P. Effect of high pressure treatments on the properties of EVOH-based food packaging materials. Innov. Food Sci. Emerg. Technol. 2005. V. 6. P. 51-58. DOI: 10.1016/j.ifset.2004.09.002.
Huang H.D., Ren P.G., Zhong G.J. Promising strategies and new opportunities for high barrier polymer packaging films. Prog. Polym. Sci. 2023. V. 144. P. 101722. DOI: 10.1016/j.progpolymsci.2023.101722.
Bai F., Chen G., Hu Y. Understanding the effect of plastic food packaging materials on food flavor: A critical review. Trends Food Sci. Technol. 2024. V. 148. P. 104502. DOI: 10.1016/J.TIFS.2024.104502.
Ge C., Fortuna C., Lei K., Lu L.X. Neat EVOH and EVOH/LDPE blend centered three-layer coextruded blown film without tie layers. Food Packag. Shelf Life. 2016. V. 8. P. 33-40. DOI: 10.1016/j.fpsl.2016.03.001.
Gavara R., Catalá R., López Carballo G. Use of EVOH for Food Packaging Applications. In: Reference Module in Food Science. 2016. DOI: 10.1016/b978-0-08-100596-5.21125-6.
Du H., Sun X., Chong X., Yang M., Zhu Z., Wen Y. A review on smart active packaging systems for food preservation: Applications and future trends. Trends Food Sci. Tech-nol. 2023. V. 141. P. 104200. DOI: 10.1016/j.tifs.2023.104200.
Tamizhdurai P., Mangesh V.L., Santhosh S. A state-of-theart review of multilayer packaging recycling: Challenges, alternatives, and outlook. J. Clean Prod. 2024. V. 447. P. 141403. DOI: 10.1016/j.jclepro.2024.141403.
Zhang Z., Huang Y., Xie Q., Liu G., Ma C., Zhang G. Functional polymerceramic hybrid coatings: Status, progress, and trend. Prog. Polym. Sci. 2024. V. 154. P. 101840. DOI: 10.1016/J.PROGPOLYMSCI.2024.101840.
Samorodnova A.P., Khrizanforov M.N., Zagidullin A.A. Electrochemical approaches to the synthesis of silicon-containing polymers. Polymer (Guildf). 2025. V. 317. P. 127925. DOI: 10.1016/J.POLYMER.2024.127925.
Vasconcelos R.L., Oliveira G.H.M., Amancio-Filho S.T., Canto L.B. Injection overmolding of polymer-metal hybrid structures: A review. Polym. Eng. Sci. 2023. V. 63. P. 691-722. DOI: 10.1002/pen.26244.
Li S., Jiang J., Geng Y. Application of silane protective materials in the concrete durability improvement in recent years: A review. Eng. Fail Anal. 2024. V. 160. P. 108140. DOI: 10.1016/j.engfailanal.2024.108140.
Lv Q., Yuan X., Guo L. Advances in production and optimization of electronicgrade polysilicon: A review of modified Siemens and silane methods. Sol. Energy Mater. Sol. Cells. 2025. V. 283. P. 113446. DOI: 10.1016/J.SOLMAT.2025.113446.
Mukherjee R., Badaik S., Pandey A.K., Bhagat A.N., Rout T.K. A hybrid coating of organometallic complex with a silane coupling compound to protect galvannealed (GA) steel from white rust without sacrificing weldability. Mater. Chem. Phys. 2023. V. 309. P. 128292. DOI: 10.1016/j.matchemphys.2023.128292.
Ou J., Dai Z., Chen Y., Kong Z., Yang R. Synthesis of a polysiloxane coating and investigation of its functional properties with high hardness and flame retardancy. J. Sol-Gel Sci. Technol. 2020. V. 95. P. 1-10. DOI: 10.1007/s10971-020-05297-w.
Zhan W., Li Y., Wang W. Study of titanium/zirconium with low polymerization water-based epoxysilane composite chemical conversion coatings on multimetals bodies of new energy vehicles. Prog. Org. Coat. 2025. V. 200. P. 109023. DOI: 10.1016/J.PORGCOAT.2024.109023.
Li H., Sun L., Li W. Application of organosilanes in titanium-containing organic-inorganic hybrid coatings. J. Mater. Sci. 2022. V. 57. P. 13845-13870. DOI: 10.1007/s10853-022-07488-y.
Chruściel J.J., Leśniak E. Modification of epoxy resins with functional silanes, polysiloxanes, silsesquioxanes, silica and silicates. Prog. Polym. Sci. 2015. V. 41. P. 67-121. DOI: 10.1016/J.PROGPOLYMSCI.2014.08.001.
Ubhale Y.S., More A.P. Antimicrobial solgel coating: a review. J. Coat. Technol. Res. 2025. V. 22. P. 527–548. DOI: 10.1007/s11998-024-01014-2.
Thomas P., Sahoo B.N., Thomas P.J., Greve M.M. Recent advances in emerging integrated anticorrosion and antifouling nanomaterial-based coating solutions. Environ. Sci. Pollut. Res. 2024. V. 31. P. 67550-67576. DOI: 10.1007/s11356-024-33825-6.
Nedel’kin V.I., Nedel’kin A. V., Izmailov B.A., Zachernyuk A.B., Solov’eva E.N., Zachernyuk B.A. Practical Application of Selected Functional Organosilicone Polymers. Polym. Sci – Ser C. 2023. V. 65. P. 162-172. DOI: 10.1134/S1811238223700418.
Bredov N.S., Kireev V. V., Polyakov V.A., Sokol’skaya I.B., Esin A.S. Modern Approaches to Obtaining Orga-nofunctional Silsesquioxanes. Polym. Sci – Ser C. 2023. V. 65. P. 180-195. DOI: 10.1134/S181123822370039X.
Serenko O.A. Polymetalorganosiloxanes as a Reflection of the Milestones in the Development of Advanced Technologies in the Chemistry of Silicones. Polym. Sci – Ser C. 2023. V. 65. P. 259-266. DOI: 10.1134/S181123822370025X.
Anisimov A.A., Minyaylo E.O., Shakirova A.R., Shchegolikhina O.I. Evolution of Organometallasiloxanes. Polym. Sci – Ser C. 2023. V. 65. P. 230-258. DOI: 10.1134/S1811238223 70042X.
Innocenzi P. Solgel processing for advanced ceramics, a perspective. Open. Ceram. 2023. V. 16. P. 100477. DOI: 10.1016/j.oceram.2023.100477.
Baskaran K., Ali M., Gingrich K. Solgel derived silica: A review of polymer-tailored properties for energy and environmental applications. Microporous Mesoporous Mater. 2022. V. 336. P. 111874. DOI: 10.1016/j.micromeso.2022.111874.
Kim Y.H., Lee I., Lee H. Solgel synthesized siloxane hybrid materials for display and optoelectronic applications. J. Sol-Gel Sci. Technol. 2023. V. 107. P. 1-14. DOI: 10.1007/s10971-021-05491-4.
Guglielmi M. From past research experiences looking to the future of sol-gel. J. Sol-Gel Sci. Technol. 2020. V. 95. P. 494-502. DOI: 10.1007/s10971-020-05267-2.
Haas K.H., Amberg-Schwab S., Rose K., Schottner G. Functionalized coatings based on inorganicorganic polymers (ORMOCER®s) and their combination with vapor deposited inorganic thin films. Surf. Coat. Technol. 1999. V. 111. P. 72-79. DOI: 10.1016/S0257-8972(98)00711-7.
Minelli M., De Angelis M.G., Doghieri F., Marini M., Toselli M., Pilati F. Oxygen permeability of novel organic-inorganic coatings: I. Effects of organicinorganic ratio and molecular weight of the organic component. Eur. Polym. J. 2008. V. 44. P. 2581-2588. DOI: 10.1016/j.eurpolymj.2008.06.006.
Toselli M., Pilati F., Marini M., Doghieri F., De Angelis M.G., Minelli M. Oxygen permeability of novel organicinorganic coatings: II. Modification of the organic component with a hydrogen-bond forming polymer. Eur. Polym. J. 2008. V. 44. P. 3256-3263. DOI: 10.1016/j.eurpolymj.2008.07.037.
Minelli M., De Angelis M.G., Doghieri F., Rocchetti M., Montenero A. Barrier properties of organic-inorganic hybrid coatings based on polyvinyl alcohol with improved water re-sistance. Polym. Eng. Sci. 2010. V. 50. P. 144-153. DOI: 10.1002/pen.21440.
Farris S., Introzzi L., Piergiovanni L. Evaluation of a biocoating as a solution to improve barrier, friction and optical properties of plastic films. Packag. Technol. Sci. 2009. V. 22. P. 69-83. DOI: 10.1002/pts.826.
Iotti M., Fabbri P., Messori M., Pilati F., Fava P. Organic-inorganic hybrid coatings for the modification of barrier properties of poly(lactic acid) films for food packaging applications. J. Polym. Environ. 2009. V. 17. P. 10-19. DOI: 10.1007/s10924-009-0120-4.
Farris S., Unalan I.U., Introzzi L., Fuentes-Alventosa J.M., Cozzolino C.A. Pullulan-based films and coatings for food packaging: Present applications, emerging opportunities, and future challenges. J. Appl. Polym. Sci. 2014. V. 131. P. 40539. DOI: 10.1002/app.40539.
Jahn A., Thümmler K., Gebke S. Utilization of Hemicelluloses as Example for Holistic Recovery of Agricultural Residues. Chem. Ing.Tech. 2020. V. 92. P. 1764-1771. DOI: 10.1002/cite.202000080.
Shabarin A.A., Kuzmin A.M., Vodyakov V.N., Shabarin I.A. Obtaining Biodegradable Composite Materials Based On Polyolefinsand Huskof Sunflower Seeds. ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2021. V. 64. N 4. Р.73-78 (in Russian). DOI: 10.6060/ivkkt.20216404.6283.
Rovera C., Ghaani M., Farris S. Nanoinspired oxygen barrier coatings for food packaging applications: An overview. Trends Food Sci. Technol. 2020. V. 97. P. 210-220. DOI: 10.1016/j.tifs.2020.01.024.
Nikolic M.V., Vasiljevic Z.Z., Auger S., Vidic J. Metal oxide nanoparticles for safe active and intelligent food packaging. Trends Food Sci. Technol. 2021. V. 116. P. 655-668. DOI: 10.1016/j.tifs.2021.08.019.
Struller C.F., Kelly P.J., Copeland N.J. Aluminum oxide barrier coatings on polymer films for food packaging applications. Surf Coat. Technol. 2014. V. 241. P. 130-137. DOI: 10.1016/j.surfcoat.2013.08.011.
Amberg-Schwab S., Müller K., Somorowsky F., Sängerlaub S. UV-Activated, Transparent Oxygen Scavenger Coating Based on Inorganic-Organic Hybrid Polymer (OR-MOCER®) with High Oxygen Absorption Capacity. Coatings. 2023. V. 13. P. 473. DOI: 10.3390/coatings13020473.
Chalaya N.M., Efremova A.A., Shchepelev A.A., Ivanenko T.A., Tsapenko I.N. Heatresistant polymer composite materials with low gas per-meability. Ross. Khim. Zhurn. 2025. V. 69. N 1. P. 55-59 (in Russian). DOI: 10.6060/rcj.2025691.11.
