RADIATION-THERMAL METHOD FOR LITHIUM-ZINC FERRITE CERAMICS MANUFACTURING
Abstract
The structural and magnetic properties of lithium-zinc ferrite ceramics of Li0.4Fe2.4Zn0.2O4 composition, which was obtained under complex high-energy action based on the use of mechanical activation of Fe2O3-Li2CO3-ZnO initial reagents mixture in AGO-2C planetary mill and subsequent its heating to a sintering temperature of 1050 °C for 140 min by ELV-6 continuous electrons beam with an electron energy of 1.4 MeV, were investigated. X-ray phase analysis showed a broadening of diffraction peaks due to the decrease in the crystallite sizes and the increase in the values of microdeformation as a result of mechanical milling. It was established that preliminary mechanical activation of the initial reagents mixture in a planetary mill allows not only to accelerate the synthesis of ferrite materials, but also to combine the both technological stages of synthesis and sintering in one stage of radiation-thermal treatment, consisting in a heating of press-billets by a high-energy electron beam to a sintering temperature. Lithium-zinc ferrite ceramics, obtained by the radiation-thermal method, is characterized by high density and low porosity as well as high values of the specific magnetization and the Curie temperature.
Forcitation:
Lysenko E.N., Surzhikov A.P., Malyshev A.V., Vlasov V.A., Nikolaev E.V. Radiation-thermal method for lithium-zinc ferrite ceramics. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2018. V. 61. N 6. P. 69-75
References
Parveen K., Juneja J.K., Sangeeta S., Raina K.K., Prakash C. Improved dielectric and magnetic properties in modified lithi-um–ferrites. Ceram. Int. 2015. V. 41. P. 3293–3297.
Cook W., Manley M. Raman characterization of - and -LiFe5O8 prepared through a solid-state reaction pathway.
J. Solid State. Chem. 2010. V. 183. P. 322326.
Rakshit S.K., Parida S.C., Naik Y.P., Venugopal V. Thermodynamic studies on lithium ferrites. J. Solid State Chem. 2011. V. 184. P. 1186-1194.
Verma V., Gairola S.P., Pandey V., Tawale J.S., Su H., Kotanala R.K. High permeability and low power loss of Ti and Zn substitution lithium ferrite in high frequency range. J. Magn. Magn. Mater. 2009. V. 321. P. 3808–3812.
Teixeira S.S., Graça M.P.F., Costa L.C. Dielectric, morphological and structural properties of lithium ferrite powders prepared by solid state method. J. Non-Crystalline Solids. 2012. V. 358. P. 1924–1929.
Gruskova A., Jancarik V., Slama J., Dosoudil R. Effect of Zn-Ti substitution on electromagnetic properties of Li ferrites. J. Magn. Magn. Mater. 2006. V. 304. P. 762–765.
Ruiz M.S., Jacobo S.E. Electromagnetic properties of lithium zinc ferrites doped with aluminum. Physica B. 2012.
V. 407. P. 3274-3277.
Vasendina E.A., Lysenko E.N., Vlasov V.A., Surzhikov A.P., Sokolovskiy A.N. The use of electron beams to increase the efficiency of solid-phase synthesis of oxide materials. Tekhnika i Tekhnologiya Silikatov. 2011. N 4. P. 6-11 (in Russian).
Naiden E.P., Minin R.V., Itin V.I., Zhuravlev V.A. Influence of radiation-thermal treatment on the phase composition and structural parameters of the SHS product based on W-type hexaferrite. Russ. Phys. J. 2013. V. 56. P. 674-680.
Surzhikov A.P., Lysenko E.N., Vlasov V.A., Vasendina E.A., Pritulov A.M. Dependence of lithium–zinc ferrospinel phase composition on the duration of synthesis in an accelerated electron beam. J. Therm. Anal. Calorim. 2012. V. 110.
N 2. P. 733-738.
Surzhikov A.P., Vasendina E.A., Lysenko E.N., Nikolaev E.V. Kinetics of phase formation in a Li2CO3-TiO2-Fe2O3 system during radiation-thermal synthesis. Perspektivnye Materialy. 2013. N 8. P. 5-10 (in Russian).
Zhuravlev V.A., Naiden E.P., Minin R.V., Itin V.I., Suslyaev V.I., Korovin E.Yu. Radiation-thermal synthesis of W-type hexaferrites. IOP Conf. Ser.: Mater. Sci. Eng. 2015. V. 81. P. 012003.
Ancharova U.V., Mikhailenko M.A., Tolochko B.P., Lyakhov N.Z., Korobeinikov M.V., Bryazgin A.A., Bezuglov V.V., Shtarklev E.A. Synthesis and staging of the phase formation for strontium ferrites in thermal and radiation thermal reactions. IOP Conf. Ser.: Mater. Sci. Eng. 2015. V. 81. Р. 012122.
Kostishin V.G., Andreev V.G., Korovushkin V.V., Chitanov D.N., Yudanov N.A., Morchenko A.T., Komlev A.S., Adamtsov A.Yu., Nikolaev A.N. Preparation of 2000NN ferrite ceramics by a complete and a short radiation-enhanced thermal sintering process. Inorg. Materials. 2014. V. 50. P. 1317.
Malyshev A.V., Lysenko E.N., Vlasov V.A., Nikolaeva S.A. Electromagnetic properties of Li0.4Fe2.4Zn0.2O4 ferrite sintered by continuous electron beam heating. Ceram. Int. 2016. V. 42. P. 16180–16183.
Zyryanov V.V. Mechanochemical synthesis of complex oxides. Usp. Khimii. 2008. V. 77. N 2. P. 107-136 (in Russian).
Kuznetsova L.I., Kuznetsov P.N., Kazbanova A.V., Zhizhaev A.M., Avvakumov E.G., Boldyrev V.V. The effect of me-chanical treatment of MoO3 (WO3) - zirconium hydroxide mixtures on their phase composition. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2008. V. 51. N 11. P. 33-36 (in Russian).
Berbenni V., Marini A., Matteazzi P., Ricceri R., Welham N.J. Solid-state formation of lithium ferrites from mechanically acti-vated Li2CO3–Fe2O3 mixtures. J. Eur. Ceram. Soc. 2003. V. 23. P. 527-536.
Boldyrev V.V. Mechanochemistry and mechanical activation of solids. Usp. Khimii. 2006. V. 75. P. 203 (in Russian).
Kavanlooee M., Hashemi B., Maleki-Ghaleh H., Kavanlooee J. Effect of annealing on phase evolution, microstructure, and magnetic properties of nanocrystalline ball-milled LiZnTi ferrite. J. Electronic materials. 2012. V. 41. P. 3082–3086.
Widatallah H.M., Ren X.L., Al-Omari I.A. The influence of TiO2 polymorph, mechanical milling and subsequent sintering on the formation of Ti-substituted spinel-related Li0.5Fe2.5O4. J. Mater. Sci. 2006. V. 41. P. 6333–6338.
Kosova N.V., Devyatkina E.T., Slobodkin A.B. Application of mechanical activation for the synthesis of cathode materials based on solid solutions. Chemistry for sustainable development. 2009. V. 17. P. 133-141.
Berbenni V., Bruni G., Milanese C., Girella A., Marini A. Synthesis and characterization of LaFeO3 powders prepared by a mixed mechanical/thermal processing route. J. Therm. Anal. Calorim. 2017. DOI: 10.1007/s10973-017-6878-z (publ. online).
Mihalache V. Thermal analysis of ball-milled Fe-14Cr-3W-0.4Ti-0.25Y2O3 ferritic steel powder. J. Therm. Anal. Calorim. 2016. V. 124. P. 11791192.
Surzhikov A.P., Lysenko E.N., Vlasov V.A., Malyshev A.V., Nikolaev E.V. Investigation of the process of ferrite formation in the Li2CO3-ZnO-Fe2O3 system under high-energy actions. Russ. Phys. J. 2013. V. 56. N 6. P. 681-685.
Lysenko E.N., Surzhikov A.P., Vlasov V.A., Nikolaev E.V., Malyshev A.V., Bryazgin A.A., Korobeynikov M.V., Mikhai-lenko M.A. Synthesis of substituted lithium ferrites under the pulsed and continuous electron beam heating. Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms. 2017. V. 392. P. 1-7.
Kuksanov N.K., Fadeev S.N., Golubenko Y.I., Kogut D.A., Korchagin A.I., Lavrukhin A.V., Nemytov P.I. Development of the model range and improve performance accelerators ELV. Problems of atomic science and technology. 2012. N 3. P. 15-18.
Kuksanov N.K., Fadeev S.N., Salimov R.A., Golubenko Y.I., Kogut D.A., Korchagin A.I., Lavrukhin A.V., Nemytov P.I., Domarov E.V., Semenov A.V. Technical facilities for improving the quality of irradiation of materials by ELV accelerators. Physics of Particles and Nuclei Letters. 2014. V. 11. N 5. P. 610-614.
Surzhikov A.P., Pritulov A.M., Lysenko E.N., Vlasov V.A., Vasendina E.A., Malyshev A.V. Analysis of the phase composi-tion and homogeneity of ferrite lithium-substituted powders by the thermomagnetometry method. J. Therm. Anal. Calorim. 2013. V. 112. P. 739-745.
Wang T, Wang H, Wang F, Li J, Zhang Q, Huang X. Certification of reference materials of Alumel, nickel and iron for Curie point. J. Therm. Anal. Calorim. 2018. V. 131. P. 1979–1985.
Nikolaev E.V., Surzhikov A.P., Lysenko E.N. Kinetic analysis of lithium-zinc ferrite synthesis by thermogravimetric method. Adv. Mat. Res. 2015. V. 1085. P. 255–259.
Zdujić M., Jovalekić C., Karanović Lj., Mitrić M. The ball milling induced transformation of α-Fe2O3 powder in air and oxygen atmosphere. Mater. Sci. Eng. A. 1999. V. 262. P. 204–213.