ВЛИЯНИЕ МЕТАЛЛА В СТРУКТУРЕ ПОРФИРИНА НА КИНЕТИКУ ЭЛЕКТРОПОЛИМЕРИЗАЦИИ И МОРФОЛОГИЮ ПЛЕНОК НА ОСНОВЕ ГИДРОКСИФЕНИЛПОРФИРИНА
Аннотация
Продемонстрирована принципиальная возможность получения пленок из ДМСО при активированном кислородом электрохимическом окислении гидроксифенилпорфирина и его цинкового комплекса. Изучена кинетика осаждения и морфология пленок. Показано, что происходит пассивация поверхности рабочего электрода при осаждении пленки порфирина-лиганда; при осаждении пленки металлокомплекса поверхность не пассивируется. Поэтому электрохимический метод позволяет сформировать достаточно толстые пленки с глобулярной структурой на базе металлокомплекса, и пленки малой толщины и слоистой структуры на базе порфирина-лиганда.
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