COORDINATION INTERACTION OF METALLOPORPHYRINS WITH NITROGEN-CONTAINING LIGANDS AS A METHOD FOR REGULATING THE FORMATION OF METAL ISOPORPHYRINATES
Abstract
The presented work is devoted to the study the possibility of using the nitrogen-containing ligands (pyridine, imidazole, 2-methylimidazole) coordination by zinc meso-tetraphenylporphyrinate as a method for regulating the formation of corresponding isoporphyrinates under the action of benzoyl peroxide in chloroform. The research was carried out in two stages. At the first stage, extra complexes of these ligands with zinc meso-tetraphenylporphyrinate in solution were obtained. The extracoordination of 2-methylimidazole with zinc porphyrinate in chloroform was studied for the first time. The extra complex stability constant and the thermodynamic parameters of the process were presented in this article. The stability range of zinc meso-tetraphenylporphyrinate extra complexes in chloroform based on the literature data and the experimental results was established: ZnTPP(Im) > ZnTPP(2-MeIm) > ZnTPP(Py). Studies of the interaction of the obtained extracomplexes with an excess of benzoyl peroxide in chloroform at the second stage of the work showed that the formation of the corresponding isoporphyrinates is possible only with ZnTPP(Py), and this process proceeds slower than with ZnTPP. During the interaction, characteristic changes in the electronic absorption spectra were observed: a decrease in the absorption bands in the visible region and an increase in the absorption bands in the near-IR region of the spectrum. It is noted that during the formation of ZnTPP isoporphyrinate(Py), a bathochromic shift of the absorption bands in the electronic absorption spectra occurs by 1-4 nm compared to ZnTPP isoporphyrinate. It was found that the more stable metalloporphyrin extra complex, the lower the probability of the formation of metal isoporphyrinate. It is shown that the introduction of coordinating additives into the "metalloporphyrin-benzoyl peroxide" system makes it possible to regulate the direction and rate of the formation of metal isoporphyrinates.
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