COMPOSITE POLYPORPHYRIN FILMS BASED ON 5,10,15,20-TETRAKIS(3-AMINOPHENYL)PORPHYRIN METAL COMPLEXES FOR ELECTROCATALYTIC OXYGEN REDUCTION
Abstract
In this work the results of studies on the electrochemical deposition of polyporphyrin films based on two different metal porphyrins: iron porphyrin and manganese porphyrin, as well as a composite film based on these two metal complexes are presents. The metalloporphyrins were deposited separately and then together on a glassy carbon electrode. The cyclic voltammogram (CV) of the composite deposition process shows both the features of the CV behavior characteristic of individual porphyrins and new changes in the CV shape and the appearance of a new peak on the cathode branch. The effect of electrodeposition parameters on the efficiency of film formation in the case of homopolymer deposition and on the composite composition in the case of co-deposition of two metal complexes was studied. For Mn(III)ClT(3-NH2Ph)P and Fe(III)ClT(3-NH2Ph)P, a change in the potential sweep rate from 20 to 100 mV/s leads to a significant increase in the film thickness. For a composite film, an increase in the potential sweep rate leads to a significant decrease in the film thickness and a change in the composition of the composite. There is no strong interaction between Mn(III)ClT(3-NH2Ph)P and Fe(III)ClT(3-NH2Ph)P in DCM solution as shown by spectral studies. The bands in the spectrum of the mixture of porphyrins are not shifted relative to the bands in the spectrum of individual compounds, which suggests the additivity of the spectral contributions when studying a mixture of these two porphyrins and a polyporphyrin film based on them. The obtained polyporphyrins were tested for catalytic activity in the reaction of oxygen electroreduction. The highest catalytic activity was observed for a composite based on two metal complexes compared with films of individual porphyrins, which suggests the presence of a synergistic effect.
References
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