АЦЕТАТ РТУТИ(II) НА ПОДЛОЖКЕ ИЗ ХИТОЗАНА В КАЧЕСТВЕ КАТАЛИЗАТОРА РЕАКЦИЙ ТРАНСВИНИЛИРОВАНИЯ АЗОЛОВ
Аннотация
Нанесение гомогенных катализаторов - соединений переходных металлов – на органические полимеры имеет большой интерес среди исследователей. Наиболее исчерпывающий анализ в этой области был опубликован в 1983 г, где подробно рассматривались результаты 1217 работ, и это число постоянно растет. Гетерогенные катализаторы часто служат очень долго, их легко отделить от реагентов и продуктов реакции и можно многократно использовать. Гомогенный катализатор на гетерогенном носителе действует так, как если бы он находился в растворе, однако одновременно он представляет собой отдельную неподвижную фазу. Исходя из вышесказанного, в этой работе мы попытались использовать хитозан в качестве носителей для ионов двухвалентных металлов, в частности ртути, заранее зная, что хитозан является хорошим лигандом для переходных металлов. Интерес к хитозанам связан с их уникальными физиологическими и экологическими свойствами, такими как биосовместимость, биодеструкция и хелатирующая способность. Описан эффективный и простой способ винилирования азолов в присутствии нанесенной на хитозан гетерогенной каталитической системы ацетата ртути(II). В результате было синтезировано несколько продуктов с высокими выходами. Разработанная методика проста в исполнении, требует меньшего количества катализатора, сокращает время реакции, исключает образование побочных продуктов и обеспечивает более высокие селективные выходы винилированных продуктов. Кроме того, можно извлекать катализатор из реакционной смеси и повторно использовать эту каталитическую систему более четырех раз. Это позволяет уменьшить загрязнение сточных вод ионами ртути.
Для цитирования:
Алексанян А.Г., Агекян М.А., Акопян Р.М., Шахатуни А.Г., Шахатуни А.А., Аттарян О.С. Ацетат ртути(II) на подложке из хитозана в качестве катализатора реакций трансвинилирования азолов. Изв. вузов. Химия и хим. технология. 2024. Т. 67. Вып. 3. С. 119-126. DOI: 10.6060/ivkkt.20246703.6942.
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