ИНГИБИТОРЫ КОРРОЗИИ ДЛЯ ЗАЩИТЫ ТЕХНОЛОГИЧЕСКОГО ОБОРУДОВАНИЯ НЕФТЕПРОМЫШЛЕННОСТИ, ЭКСПЛУАТИРУЕМОГО В СЕРОВОДОРОДСОДЕРЖАЩИХ СРЕДАХ
Аннотация
Данная обзорная статья посвящена проблеме коррозии технологического оборудования, такого как: колонны установок первичной переработки нефти, скважинные насосы, обсадные колонны, резервуары хранения нефти, системы трубопроводов, в нефтепромышленности, в частности, в условиях эксплуатации в сероводородсодержащих средах. Рассматривается способ защиты от коррозии наиболее уязвимых элементов технологических схем с использованием метода изменения состава среды: введения в рабочие жидкости специальных реагентов, замедляющих реакции разрушения металлов – ингибиторов коррозии. Анализ литературных источников выявил наличие множества научных коллективов, участвующих в модификации имеющихся и получению новых ингибирующих сероводородную коррозию композиций. Особое внимание уделяется азотсодержащим ингибиторам, наиболее часто составляющим предмет интереса мирового научного сообщества коррозионистов по разработке ингибиторов, поскольку демонстрируют высокую эффективность в предотвращении коррозии, вызванной воздействием сероводорода. Авторами рассматриваются такие классы соединений, как: высшие алифатические моно- и диамины, амиды, амидоамины (в том числе имидазолины), азометины (основания Шиффа), четвертичные аммонийные соединения, фенольные основания Манниха, эфирамины и азолы. В статье подробно описываются особенности химического состава разработанных реагентов, свойства ингибиторов и их способность снижать скорость общей коррозии и наводороживания металлов в агрессивных средах нефтепереработки. Данная обзорная статья позволит систематизировать имеющиеся научные труды, посвященные методу защиты оборудования нефтеперерабатывающей отрасли с применением азотсодержащих органических соединений, и может быть использована как основа для дальнейших научных изысканий в сфере получения промышленно важных продуктов, в том числе из отходов действующих производств.
Для цитирования:
Леонтьева М.Е., Агаркова М.О., Демидова Ю.В., Демидов П.А., Дронов С.В. Ингибиторы коррозии для защиты технологического оборудования нефтепромышленности, эксплуатируемого в сероводородсодержащих средах (Обзор). Изв. вузов. Химия и хим. технология. 2025. Т. 68. Вып. 7. С. 6-19. DOI: 10.6060/ivkkt.20256807.7213.
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