THEORETICAL AND EXPERIMENTAL APPROACHES IN THE STUDY OF ELECTROCHEMICAL AND THERMODYNAMIC PROPERTIES OF POLYFUNCTIONAL ORGANIC COMPOUNDS IN LIQUID-PHASE AND HETEROPHASE SYSTEMS

  • Mikhail I. Bazanov Ivanovo State University of Chemistry and Technology
  • Nadezhda M. Berezina Ivanovo State University of Chemistry and Technology
  • Sergey N. Gridchin Ivanovo State University of Chemistry and Technology
  • Olga N. Krutova Ivanovo State University of Chemistry and Technology
  • Galina G. Gorboletova Ivanovo State University of Chemistry and Technology
  • Svetlana A. Bychkova Ivanovo State University of Chemistry and Technology
  • Alexander I. Lytkin Ivanovo State University of Chemistry and Technology
  • Natalia V. Chernyavskaya Ivanovo State University of Chemistry and Technology
  • Viktor V. Chernikov Ivanovo State University of Chemistry and Technology
  • Aleksey V. Volkov Ivanovo State University of Chemistry and Technology
DOI: https://doi.org/10.6060/ivkkt.20236607.6839j
Keywords: metalloporphyrins, aminocarbonic acids, complexes, cyclic voltammetry, electrocatalysis, calorimetry, potentiometry, equilibrium constant, enthalpy, entropy

Abstract

The publication reflects the experimental substantiation and fundamental development of some important ideas of the theory of the mutual influence of functional substitution in complex molecules of macrocyclic and chelating compounds on their coordination, solvation and redox properties, as well as the formation of algorithms for searching useful functions of these compounds. Researchers of the Analytical Chemistry Department of the Ivanovo State University of Chemistry and Technology have been studying the electrochemical and thermodynamic behavior of porphyrins, complexones, amino acids, peptides and the corresponding complexes with d- and f-metal ions, their influence on coordination, solvation and catalytic processes for a number of years. The results obtained together with the literature data are discussed in the review.

For citation:

Bazanov M.I., Berezina N.M., Gridchin S.N., Krutova O.N., Gorboletova G.G., Bychkova S.A., Lytkin A.I., Chernyavskaya N.V., Chernikov V.V., Volkov A.V. Theoretical and experimental approaches in the study of electrochemical and thermodynamic properties of polyfunctional organic compounds in liquid-phase and heterophase systems. ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2023. V. 66. N 7. P. 98-110. DOI: 10.6060/ivkkt.20236607. 6839j.

 

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Published
2023-05-17
How to Cite
Bazanov, M. I., Berezina, N. M., Gridchin, S. N., Krutova, O. N., Gorboletova, G. G., Bychkova, S. A., Lytkin, A. I., Chernyavskaya, N. V., Chernikov, V. V., & Volkov, A. V. (2023). THEORETICAL AND EXPERIMENTAL APPROACHES IN THE STUDY OF ELECTROCHEMICAL AND THERMODYNAMIC PROPERTIES OF POLYFUNCTIONAL ORGANIC COMPOUNDS IN LIQUID-PHASE AND HETEROPHASE SYSTEMS. ChemChemTech, 66(7), 98-110. https://doi.org/10.6060/ivkkt.20236607.6839j
Issue
Vol 66 No 7 (2023)
Section
CHEMISTRY (inorganic, organic, analytical, physical, colloid and high-molecular compounds)

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