РЕАКЦИОННАЯ СПОСОБНОСТЬ АЛЮМООКСИДНЫХ ПРЕКУРСОРОВ ДЛЯ ТВЕРДОФАЗНОГО ОБРАЗОВАНИЯ ШПИНЕЛИ MgAl2O4
Аннотация
Сопоставлена реакционная способность различных алюмооксидных прекурсоров в реакции образования магнезиальной шпинели: промышленного производства (корундового порошка КП (KP), глиноземов: металлургического ГК (GK), неметаллургического Г-00 (G-00), реактивного РГ (RG)) и продукта горения ксерогеля из нитрата алюминия с лимонной кислотой в условиях механоактивирующей обработки и без нее. Проанализированы ИК-спектры корунда и периклаза после механической обработки разного типа (ударно-истирающей в планетарной мельнице, истирания в шаро-кольцевой мельнице). Установлено, что кратковременное воздействие не только активировало компоненты, но и способствовало разрушению адсорбционных соединений на стадии подготовки. Проанализировано влияние механоактивации реагентов на выход шпинели. Установлено, что алюмооксидный продукт горения ксерогеля без отжига являлся рентгеноаморфным, что предполагало его высокую химическую активность. При его использовании обнаружено более полное связывание исходных реагентов в продукт по сравнению со смесью периклаза и корунда. Даже в отсутствие механоактивации компонентов удавалось достичь высокого выхода шпинели (до 80%). Полученные значения эффективных констант скорости реакции свидетельствуют о большей результативности механической обработки, включающей в себя ударную компоненту, при совместной активации периклаза и корунда/глинозема. Совместная обработка реагентов в планетарной мельнице (ПМ) позволила увеличить скорость реакции в 5-6,5 раз, тогда как истирание в шаро-кольцевой мельнице – всего в 1,7 раза. Предварительная обработка одного из компонентов исходной смеси в ПМ наиболее целесообразна для периклаза, поскольку она дала возможность ускорить реакцию в ~ 5 раз, а также наиболее выгодна энергетически и технологически из-за обработки только одного компонента пониженной твердости. Применение в синтезе шпинели продукта горения ксерогеля весьма эффективно, т.к. ускорило процесс в ~4 раза даже без предварительной активации механическим способом.
Для цитирования:
Филатова Н.В., Косенко Н.Ф., Артюшин А.С., Малоиван М.С., Зонина И.И., Власенков А.С. Реакционная способность алюмооксидных прекурсоров для твердофазного образования шпинели MgAl2O4. Изв. вузов. Химия и хим. технология. 2024. Т. 67. Вып. 12. С. 15-24. DOI: 10.6060/ivkkt.20246712.7152.
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